VUV 5d-4f luminescence of Gd3+ and Lu3+ ions in the CaF2 host

被引：14
|
作者：
Makhov, V. N. [1 ,2 ]
Batygov, S. Kh. [3 ]
Dmitruk, L. N. [3 ]
Kirm, M. [2 ]
Vielhauer, S. [2 ]
Stryganyuk, G. [4 ]
机构：
[1] Russian Acad Sci, PN Lebedev Phys Inst, Moscow 119991, Russia
[2] Univ Tartu, Inst Phys, EE-51014 Tartu, Estonia
[3] Russian Acad Sci, Inst Gen Phys, Moscow 119991, Russia
[4] DESY, HASYLAB, D-22607 Hamburg, Germany
来源：
PHYSICS OF THE SOLID STATE | 2008年 / 50卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
D O I：
10.1134/S1063783408090059
中图分类号：
O469 [凝聚态物理学];
学科分类号：
070205 ;
摘要：
The first observation and characterization of Lu3+ 4f(13)5d-4f(14) luminescence from the CaF2 : Lu3+ crystal are reported, and the multisite structure in the spectra of Ce3+, Gd3+, and Lu3+ ions in the CaF2 host is analyzed with the high-resolution VUV spectroscopy technique using synchrotron radiation. It is shown that vibronic structure in the emission and excitation spectra of interconfigurational transitions in Gd3+ and Lu3+ ions doped into CaF2 differs from that observed for Ce3+ ions entering mainly at the tetragonal (C-4v) sites. However, the exact types of sites in which the Gd3+ and Lu3+ ions reside in a CaF2 lattice cannot be identified using only the obtained experimental spectroscopic data.
引用
收藏
页码：1625 / 1630
页数：6
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