Synthesis and characterization of novel phthalocyanines with four 17-membered diazadithiamonooxa macrocycles

被引:0
|
作者
Sesalan, FU [1 ]
Okur, AI [1 ]
机构
[1] Istanbul Tech Univ, Dept Chem, TR-80626 Istanbul, Turkey
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中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
New phthalocyanines, (M = Cu, Zn, Ni) substituted with four 17-membered N2S2O macrocycles have been prepared starting from 1,5-bis(2'-aminophenylthia)-3-oxapentane (1a), which was tosylated and then subsequently reacted with 1,2-dibromo-4,5-bis(bromomethyl)benzene to form the macrocyclic structure (2a). The phthalocyanines (3) - (5) are soluble in chloroform, DMF, DMSO and pyridine.
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页码:1525 / 1537
页数:13
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