Multidimensional tunneling in terms of complex classical mechanics: Wave functions, energy splittings, and decay rates in nonintegrable systems

被引:24
|
作者
Takada, S [1 ]
机构
[1] INST MOLEC SCI,DIV THEORET STUDIES,OKAZAKI,AICHI 444,JAPAN
来源
JOURNAL OF CHEMICAL PHYSICS | 1996年 / 104卷 / 10期
关键词
D O I
10.1063/1.471029
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A semiclassical theory of multidimensional tunneling is formulated to calculate the tunneling wave function, energy splitting in a double well and decay rate constant from a metastable state. First, the tunneling wave function is calculated by analytic continuation of a quantized torus prepared in analytic forms using either the Chapman-Garrett-Miller method or the Birkhoff-Gustavson normal form method. For a weakly nonintegrable system, tunnelings are confirmed to be classified into two qualitatively different domains; pure tunneling in the I region and mixed tunneling in the C region. Semiclassical wave functions agree with quantum mechanical ones within a few percent both in classically allowed and tunneling regions. Breakdown of this simple picture is exemplified for cases of relatively strong couplings. Second, expressions of the tunneling energy splitting in a double well potential and the decay rate from a metastable state are derived. The wave function near a well formulated above is connected with the semiclassical Green's function in the deep tunneling region. The latter is expressed by complex trajectories which start from the complex quantized torus. A preliminary numerical comparison with the quantum mechanical value is also done for the energy splitting. (C) 1996 American Institute of Physics.
引用
收藏
页码:3742 / 3759
页数:18
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