Complex formation between aluminium(III) and two pyridine derivatives: 2-hydroxynicotinic and 3-hydroxypicolinic acid

被引:0
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作者
Di Marco, VB
Tapparo, A
Bertani, R
Bombi, GG
机构
[1] Univ Padua, Dipartimento Chim Inorgan Metallorgan & Anali, I-35131 Padua, Italy
[2] CNR, Ctr Chim Composti Metallorg, I-35131 Padua, Italy
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中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
The chemical interactions between aluminium(III) and two pyridinic ligands of possible biological relevance, 2-hydroxynicotinic acid (HNic) and 3-hydroxypicolinic acid (HPic), in aqueous 0.6m (Na)Cl at 25 degrees C, have been investigated by means of potentiometric titrations. In both cases only mononuclear complexes and their deprotonation products are formed. The qualitative and quantitative results obtained have been confirmed in part by UV-spectrophotometry and H-1 NMR spectroscopy.
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页码:535 / 546
页数:12
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