Multicomponent Reaction of Phosphines, Benzynes, and CO2: Facile Synthesis of Stable Zwitterionic Phosphonium Inner Salts

被引：24

作者：

Xie, Pei ^{[1
]}

Yang, Shoushan ^{[1
]}

Guo, Yuyu ^{[1
]}

Cai, Zhihua ^{[1
]}

Dai, Bin ^{[1
]}

He, Lin ^{[1
]}

机构：

[1] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, Shihezi 832000, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 85卷 / 14期

基金：

中国国家自然科学基金;

关键词：

STEP SIMULTANEOUS CONSTRUCTION; COUPLING INVOLVING ARYNES; DIELS-ALDER REACTION; SELECTIVE SYNTHESIS; TANDEM REACTION; C-P; ACCESS; CYCLOADDITION; ISOQUINOLINES; DERIVATIVES;

D O I：

10.1021/acs.joc.0c00745

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The first synthesis of benzyne-derived stable zwitterions is reported. Benzynes generated in situ from 2-(trimethylsilyl)aryl triflates undergo a multicomponent reaction with phosphines and CO2 to produce the stable 1,5-zwitterionic species in moderate to excellent isolated yields, which provides a novel method for the preparation of phosphonium inner salts under mild and transition-metal-free conditions.

引用

页码：8872 / 8880

页数：9

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