Synthesis and Peroxidase-Like Activity of Cobalt@Carbon-Dots Hybrid Material

被引:25
|
作者
Guo, Yali [1 ]
Liu, Xiaoyu [1 ]
Yang, Chengduan [1 ]
Wang, Xudong [1 ]
Wang, Dan [1 ]
Iqbal, Anam [1 ]
Liu, Weisheng [1 ]
Qin, Wenwu [1 ]
机构
[1] Lanzhou Univ, Key Lab Nonferrous Met Chem & Resources Utilizat, Lanzhou 730000, Peoples R China
基金
美国国家科学基金会;
关键词
carbon; cobalt; fluorescence; hybrid materials; radical reactions; GRAPHENE OXIDE; COLORIMETRIC DETECTION; ALLOY NANOPARTICLES; CATALYTIC-ACTIVITY; DEGRADATION; NANOCOMPOSITES; REDUCTION; NANODOTS; MIMICS; WATER;
D O I
10.1002/cctc.201500263
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A cobalt@carbon-dots (Co@C-dots) hybrid material is successfully prepared and well characterized. The hybrid material exhibits intrinsic peroxidase-like activity and can be utilized for the degradation of methylene blue; it shows enhanced catalytic activities compared with bare Co nanoparticles or C-dots. The good catalytic performance of the hybrid material may be attributed to synergistic effects between the Co nanoparticles and C-dots. Furthermore, the catalytic mechanism of the Co@C-dots hybrid material is also studied by using steady-state and time-resolved fluorometric analysis, which reveals that Co@C-dots can effectively decompose H2O2 to produce reactive hydroxyl radicals (OH). These results suggest that the Co@C-dots hybrid material could be a promising material applied for biochemical analysis and water treatment.
引用
收藏
页码:2467 / 2474
页数:8
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