Fine organic particle, formaldehyde, acetaldehyde concentrations under and after the influence of fire activity in the atmosphere of Riverside, California

Concentrations of gas-phase organic carbons (formaldehyde (HCHO) and acetaldehyde (CH3CHO)) and fine particle-phase carbons (organic carbon (OC) and elemental carbon (EC)) were measured under and after the influence of fire activity in southern California. The measurement was conducted after the start of the wildfire activities from October 27 through November 6, 2003 at a site in Riverside, southern California. Under the influence of the fire activities, HCHO, CH3CHO and EC concentrations were found to be over two times as high as those after the fire activities ended. The total lifetime cancer risk estimated by HCHO and CH3CHO concentrations measured was significantly higher under the influence of the wildfire activities than that after the activities ended. OC showed a larger difference in concentrations between the two event periods as compared with gas-phase organic carbons and EC. OC/EC ratios ranged from 3.7 to 12.5 during the study period with the highest OC/EC ratio observed when the study area was under the influence of the fire activities. Correlation analysis and multiple linear regressions between OC/EC concentrations and visibility were performed. It was found that the visibility was even worse under the influence of fire activity as compared to the period after fire activity ended. EC was a stronger contributor to the visibility reduction compared to OC. The influence of air mass pathways on HCHO, CH3CHO, OC, and EC concentrations during the wildfire activities was addressed using a backward trajectory model developed by NOAA. (C) 2008 Elsevier Inc. All rights reserved.