Electrons, excitons and hydrogen bonding: electron-promoted desorption from molecular ice surfaces

被引：9

作者：

Marchione, Demian ^{[1
,2
]}

McCoustra, Martin R. S. ^{[1
]}

机构：

[1] Heriot Watt Univ, Inst Chem Sci, Edinburgh EH14 4AS, Midlothian, Scotland

[2] CALTECH, Jet Prop Lab, Div Sci, 4800 Oak Grove Dr, Pasadena, CA 91109 USA

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2016年 / 18卷 / 43期

关键词：

GAUSSIAN-BASIS SETS; WATER ICE; INDUCED AMORPHIZATION; LY-ALPHA; ENERGY; METHANOL; INTERSTELLAR; RADIATION; BENZENE; CHEMISTRY;

D O I：

10.1039/c6cp05814k

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Desorption of benzene (C6H6) from thick methanol (CH3OH) and diethyl ether (CH3CH2OCH2CH3) ices during irradiation with 250 eV electrons is reported and compared with our previous work on C6H6 desorption from water (H2O) ice systems. C6H6 electron-promoted desorption (EPD) is seen to be sensitive to the chemical nature of the substrate reflecting both the importance of the excitations localised around the O-atom versus those involving the C-atom; and the role of hydrogen bonding interactions in transporting non-dissociative electronic excitation to the substrate/C6H6 interfaces during the electron irradiation.

引用

页码：29747 / 29755

页数：9

共 50 条

[1] Efficient electron-promoted desorption of benzene from water ice surfaces
Marchione, Demian
Thrower, John D.
McCoustra, Martin R. S.
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2016, 18 (05) : 4026 - 4034
[2] Electron-Promoted Desorption from Water Ice Surfaces: Neutral Gas Phase Products
Abdulgalil, Ali G. M.
Rosu-Finsen, Alexander
Marchione, Demian
Thrower, John D.
Collings, Mark P.
McCoustra, Martin R. S.
ACS EARTH AND SPACE CHEMISTRY, 2017, 1 (04): : 209 - 215
[3] Electron-Promoted X-Type Ligand Displacement at CdSe Quantum Dot Surfaces
Hartley, Carolyn L.
Dempsey, Jillian L.
NANO LETTERS, 2019, 19 (02) : 1151 - 1157
[4] Molecular hydrogen desorption from amorphous surfaces at low temperature
Vidali, G.
Li, L.
JOURNAL OF PHYSICS-CONDENSED MATTER, 2010, 22 (30)
[5] Electron- and photon-stimulated desorption of K from ice surfaces
Yakshinskiy, BV
Madey, TE
JOURNAL OF GEOPHYSICAL RESEARCH-PLANETS, 2001, 106 (E12) : 33303 - 33307
[6] Anti-bonding driving caused by electron emission: halogen desorption from Si surfaces
Miyamoto, Y
SOLID STATE COMMUNICATIONS, 2001, 117 (12) : 727 - 732
[7] Electron stimulated desorption of negative and positive hydrogen ions from hydrogenated silicon surfaces
Hoffman, A
Petravic, M
PHYSICAL REVIEW B, 1996, 53 (11): : 6996 - 6998
[8] STUDIES OF HYDROGEN DESORPTION FROM COBALT SURFACES
CABRERA, AL
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A-VACUUM SURFACES AND FILMS, 1993, 11 (01): : 205 - 208
[9] DESORPTION FROM METAL SURFACES BY LOW-ENERGY ELECTRONS
MENZEL, D
GOMER, R
JOURNAL OF CHEMICAL PHYSICS, 1964, 41 (11): : 3311 - &
[10] Desorption induced by excited electrons from semiconductor surfaces (I) - Desorption induced by electron-/nole-injection into halogen-adsorbed silicon surfaces
Shudo, Kenichi
Tanaka, Masatoshi
Shinku/Journal of the Vacuum Society of Japan, 2006, 49 (10) : 600 - 604

← 1 2 3 4 5 →