1,2,3,4,5,6-hexasila-7,8-distannabicyclo[2.2.2]octanes:: A novel approach toward bicyclo derivatives of group 14 elements

被引：7
|
作者：
Schürmann, M [1 ]
Uhlig, F [1 ]
机构：
[1] Univ Dortmund, Fachbereich Chem, D-44221 Dortmund, Germany
来源：
ORGANOMETALLICS | 2002年 / 21卷 / 05期
关键词：
D O I：
10.1021/om010801q
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Stannasilanes of the 1,2,3,4,5,6-hexasila-7,8-distannabicyclo[2.2.2]octane type (Me10R4Si6Sn2: R = Me, 5; R = Ph, 6) were synthesized by the reaction of 1,4-dihalogen-substituted decamethylcyclohexasilanes (Si6Me10X2: X = F, 1; X = Cl, 2) with diorganodichlorostannanes (R2SnCl2: R = Me, 3; R = Ph, 4) in the presence of magnesium. Compounds 5 and 6 were characterized by NMR, MS, and elemental analysis. The solid-state structure of 6 was determined by X-ray crystallography.
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收藏
页码：986 / 988
页数：3
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