Probing the active catalytic sites of zeolites with benzyl chloride

被引：8

作者：

van Herwijnen, HWG ^{[1
]}

Brinker, UH ^{[1
]}

机构：

[1] Univ Vienna, Inst Organ Chem, A-1090 Vienna, Austria

来源：

TETRAHEDRON | 2002年 / 58卷 / 24期

关键词：

zeolite; catalytic sites; benzyl chloride;

D O I：

10.1016/S0040-4020(02)00409-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Zeolites contain numerous catalytic sites. In order to conduct organic chemistry properly, it is necessary to know which site catalyzes the reaction. The conversion of benzyl chloride was tested as a probe reaction. Different products are obtained when the reaction is catalyzed by a Bronsted acidic site instead of a Lewis acidic site. Basic catalysis, water content and coke formation complicate the probe reaction. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：4963 / 4967

页数：5

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