Synthesis and structural characterization of magnesium complexes bearing phenanthrene imine derivative ligands

被引：11
|
作者：
Gao, Bo [1 ,2 ]
Xin, Lan [1 ]
Gao, Wei [1 ]
Hao, Zhi-Qiang [1 ]
Xin, Xiao-Zhi [1 ]
Wu, Qiao-Lin [1 ]
Mu, Ying [1 ]
机构：
[1] Jilin Univ, Sch Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Polymer Ecomat, Changchun 130022, Peoples R China
来源：
POLYHEDRON | 2013年 / 63卷
基金：
中国国家自然科学基金;
关键词：
Phenanthrene imine; Magnesium complexes; Radical anion; Enediamido ligands; BIDENTATE NITROGEN LIGANDS; ORGANOMETALLIC CHEMISTRY; HOMOGENEOUS CATALYSIS; MOLECULAR-STRUCTURE; CHROMIUM COMPLEXES; CALCIUM COMPLEXES; PALLADIUM; CRYSTAL; ALKYNES; POLYMERIZATION;
D O I：
10.1016/j.poly.2013.07.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reduction reactions of the phenanthrene-o-aryliminoquinone with 0.5 equiv of magnesium in tetrahydrofuran afford the bisligated magnesium complexes [(Ar)piq](2)Mg(thf) (1a, Ar = 2,6-Me2C6H3; 1b, Ar = 2,6-(Pr2C6H3)-Pr-i). 1a can be further reduced by magnesium to oxygen-bridged dinuclear complex [(mu-O)(Ar-)piqMg(thf)(2)](2) (2). Similar reduction reactions of the N,N-bis(arylimino)phenanthrene with magnesium give bis(arylimino)phenanthrene magnesium complexes (Ar1,Ar2)bipMg(thf)(3) (3, Ar-1 = Ar-2 = 2,6-Me2C6H3: 4, Ar-1 = Ar-2 = 2,6-(Pr2C6H3)-Pr-i: 5, Ar-1 = 2,6-Me2C6H3, Ar-2 = 2,6-(Pr2C6H3)-Pr-i). All the complexes were well characterized and the molecular structures of 1b, 2, 3, and 5 were established by X-ray diffraction analysis. (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码：91 / 95
页数：5
相关论文
共 50 条
  • [1] Chromium complexes supported by phenanthrene-imine derivative ligands: synthesis, characterization and catalysis on isoprene cis-1,4 polymerization
    Gao, Bo
    Luo, Xuyang
    Gao, Wei
    Huang, Long
    Gao, Si-meng
    Liu, Xiaoming
    Wu, Qiaolin
    Mu, Ying
    DALTON TRANSACTIONS, 2012, 41 (09) : 2755 - 2763
  • [2] Structural characterization and polymerization studies of nickel bromide complexes bearing azolate-imine ligands
    Peoples, Brian C.
    Caris, Rodrigo
    Valderrama, Mauricio
    Rojas, Rene
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [3] New Palladium (II) Complexes Bearing Benzopyran Derivative Ligands: Synthesis and Characterization
    Mostafa, A. M.
    Hanafy, A. I.
    Abd El-Rahman, Naglaa M.
    El-Sayed, M. M.
    EGYPTIAN JOURNAL OF CHEMISTRY, 2012, 55 (01): : 57 - 72
  • [4] Mono and bimetallic nickel bromide complexes bearing azolate-imine ligands: Synthesis, structural characterization and ethylene polymerization studies
    Caris, Rodrigo
    Peoples, Brian C.
    Valderrama, Mauricio
    Wu, Guang
    Rojas, Rene
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (12) : 1795 - 1801
  • [5] Synthesis and structural characterization of novel ruthenium(II) complexes bearing hydroxypicolinato ligands
    Nakasone, Takayuki
    Nishioka, Takanori
    Asato, Eiji
    Kinoshita, Isamu
    Takara, Satoshi
    POLYHEDRON, 2012, 45 (01) : 152 - 157
  • [6] Chromium Complexes with Acenaphthene Imine Derivative Ligands Synthesis and Catalysis on Diene Polymerization
    Gao, Bo
    Gao, Wei
    Wu, Qiaolin
    Luo, Xuyang
    Zhang, Jingshun
    Su, Qing
    Mu, Ying
    ORGANOMETALLICS, 2011, 30 (20) : 5480 - 5486
  • [7] Chromium complexes bearing pyrazolyl-imine-phenoxy/pyrrolide ligands: Synthesis, characterization, and use in ethylene oligomerization
    Bergamo, Adao L.
    Da Cas, Halana K.
    Rambo, Raoni S.
    Schwalm, Cristiane S.
    Casagrande, Adriana C. A.
    Stieler, Rafael
    Casagrande, Osvaldo L., Jr.
    CATALYSIS COMMUNICATIONS, 2016, 86 : 77 - 81
  • [8] Synthesis and Structural Characterization of Palladium Dicarbene Complexes Bearing Labile Co-Ligands
    Huynh, Han Vinh
    Seow, Hui Xian
    AUSTRALIAN JOURNAL OF CHEMISTRY, 2009, 62 (09) : 983 - 987
  • [9] Synthesis, structural characterization and in vitro anticancer activity of two new nickel complexes bearing imine bonds
    Ay, Burak
    Gonul, Ilyas
    Demir, Burcu Saygideker
    Saygideger, Yasemin
    Kani, Ibrahim
    INORGANIC CHEMISTRY COMMUNICATIONS, 2020, 114
  • [10] Synthesis and catalytic application of magnesium complexes bearing pendant indolyl ligands
    Peng, Kuo-Fu
    Chen, Yun
    Chen, Chi-Tien
    DALTON TRANSACTIONS, 2015, 44 (20) : 9610 - 9619
12345