ESR studies on poly(methyl acrylate) radicals to estimate their dominant structure

被引：6
|
作者：
Sugiyama, Y
机构：
[1] Adv. Technol. Research Laboratories, Nippon Steel Corporation, Kawasaki 211, 1618 Ida, Nakahara-ku
来源：
CHEMISTRY LETTERS | 1996年 / 11期
关键词：
D O I：
10.1246/cl.1996.951
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Electron Spin Resonance (ESR) examinations of the propagating radicals in the polymerization of methyl acrylate (MA) and methyl acrylate-alpha-d(MA-d) in the frozen state have been made. Selective deuteration of MA showed that the propagating radicals have the chain - end(I) and not the midchain (II) structure. The stable conformation of poly (methyl acrylate) (poly(MA)) radical was also determined.
引用
收藏
页码：951 / 952
页数：2
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