Substrate dependent structural and electrical properties of Bi2Cu0.1V0.9O5.35 solid electrolyte thin films

被引：10
|
作者：
Nimat, R. K. [2 ]
Joshi, R. S. [1 ]
Pawar, S. H. [1 ]
机构：
[1] Shivaji Univ, Dept Phys, Sch Energy Studies, Kolhapur 416004, MS, India
[2] Balasaheb Desai Coll, Dept Phys, Satara 415206, MS, India
来源：
JOURNAL OF ALLOYS AND COMPOUNDS | 2008年 / 466卷 / 1-2期
关键词：
Chemical synthesis; X-ray diffraction; Ionic conduction; Electronic transport; Grain boundaries; Thin films;
D O I：
10.1016/j.jallcom.2007.11.051
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
High ion conducting room temperature stabilized gamma-Bi2Cu0.1V0.9O5.35 has been successfully synthesized in thin film form on glass and alumina substrates. The films were characterized for their structural properties like XRD, SEM, EDAX and AFM. Bi2Cu0.1V0.9O5.35 films deposited on alumina substrate showed single-phase nature with tetragonal crystal structure. The AFM study reveals the considerable change in growth morphology on alumina substrate. The temperature dependent ionic conductivity of Bi2Cu0.1V0.9O5.35 films synthesized on glass and alumina substrates were studied using impedance spectroscopy. The high ionic conductivity has been observed at lower temperature for Bi2Cu0.1V0.9O5.35 thin films synthesized on alumina substrates. With these comparisons, alumina substrate proves its candidature for deposition of Bi2Cu0.1V0.9O5.35 films for solid oxide fuel cell applications. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：341 / 351
页数：11
相关论文
共 50 条
  • [1] Temperature dependent conductivity and dielectric properties of Bi2V0.9Cu0.1O5.35 solid electrolyte thin films
    Nimat, R. K.
    Joshi, R. S.
    Pawar, S. H.
    MATERIALS SCIENCE AND ENGINEERING B-SOLID STATE MATERIALS FOR ADVANCED TECHNOLOGY, 2007, 137 (1-3): : 93 - 98
  • [2] AC Conductivity of Bi2Cu0.1V0.9O5.35 Films for Fuel Cell Application
    Nimat, R. K.
    Lokare, S. A.
    Pawar, S. H.
    SOLID STATE PHYSICS: PROCEEDINGS OF THE 55TH DAE SOLID STATE PHYSICS SYMPOSIUM 2010, PTS A AND B, 2011, 1349 : 955 - +
  • [3] Spray pyrolytic deposition of solid electrolyte Bi2V0.9Cu0.1O5.35 films
    Nimat, R. K.
    Betty, C. A.
    Pawar, S. H.
    APPLIED SURFACE SCIENCE, 2006, 253 (05) : 2702 - 2707
  • [4] Synthesis of fuel cell grade Bi2Co0.1V0.9O5.35 solid electrolyte thin films
    Joshi, R. S.
    Nimat, R. K.
    Pawar, S. H.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 471 (1-2) : 461 - 465
  • [5] Relaxation studies of spray deposited Bi2Co0.1V0.9O5.35 solid electrolyte thin films on stainless steel substrate
    Joshi, Rajeev
    Mishra, R.
    Pawar, S. H.
    IONICS, 2009, 15 (04) : 453 - 458
  • [6] Relaxation studies of spray deposited Bi2Co0.1V0.9O5.35 solid electrolyte thin films on stainless steel substrate
    Rajeev Joshi
    R. Mishra
    S. H. Pawar
    Ionics, 2009, 15 : 453 - 458
  • [7] Synthesis and Characterization of Bi2Mn0.1V0.9O5.35-δ Thin Films
    Guo Ming
    Wu Lanying
    Liu Changxin
    Zhou Songhua
    MATERIALS ENGINEERING FOR ADVANCED TECHNOLOGIES, PTS 1 AND 2, 2011, 480-481 : 639 - +
  • [8] SYNTHESIS AND CHARACTERIZATION OF Bi2Cu0.1V0.9O5.35-δ SOLID ELECTROLYTE VIA CHEMICAL SOLUTION PROCESS
    Guo Ming
    Meng Xiang-Jian
    Yang Ping-Xiong
    Chu Jun-Hao
    JOURNAL OF INFRARED AND MILLIMETER WAVES, 2009, 28 (04) : 259 - 262
  • [9] Synthesis and characterization of nanoscale Bi2Cu0.1V0.9O5.35 powders by solution-based chemical methods
    Guo, M.
    Deng, H.
    Yang, P.
    MATERIALS SCIENCE-POLAND, 2009, 27 (04): : 1055 - 1066
  • [10] Microstructural, electrical, and mechanical characterization of Bi2Cu0.1V0.9O5.35 (BICUVOX) ceramics fabricated from co-precipitated precursor powders
    Sabolsky, Edward M.
    Razmyar, Soheil
    Sabolsky, Katarzyna
    JOURNAL OF MATERIALS SCIENCE, 2013, 48 (02) : 733 - 743
12345