Electrochemical and spectral properties of the polymer form of Cu(II) complex with N,N′-bis(salicylidene)-1,3-propylenediamine

被引：3

作者：

Golyakov, A. M. ^{[1
]}

Shchukarev, A. V. ^{[2
]}

Ardasheva, L. P. ^{[1
]}

Borisov, A. N. ^{[1
]}

机构：

[1] Herzen Russian State Pedag Univ, St Petersburg 191186, Russia

[2] Umea Univ, S-90187 Umea, Sweden

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2013年 / 83卷 / 03期

关键词：

FILMS;

D O I：

10.1134/S1070363213030031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A conductive polymer based on the Cu(II) complex with N,N'-bis(salicylidene)-1,3-propylenediamine was obtained electrochemically. The optimal mode of the synthesis of the polymer under potentiostatic conditions was found. We determined the charge diffusion coefficient and activation barrier and elucidated the nature of the limiting step of the charge transfer in the polymer bulk in the electrolyte medium. The azomethine base, Cu(II) complex, and its polymer form in the oxidized and reduced states were characterized by X-ray photoelectron spectroscopy and electron absorption spectroscopy.

引用

页码：423 / 429

页数：7

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