Formation of Azaborines by Photoelimination of B,N-Heterocyclic Compounds

被引：85

作者：

Lu, Jia-Sheng ^{[1
]}

Ko, Soo-Byung ^{[1
]}

Walters, Nicholas R. ^{[1
]}

Kang, Youngjin ^{[2
]}

Sauriol, Francoise ^{[1
]}

Wang, Suning ^{[1
]}

机构：

[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada

[2] Kangwon Natl Univ, Div Sci Educ, Chunchon 200701, South Korea

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 17期

基金：

加拿大自然科学与工程研究理事会;

关键词：

azaborines; boron; fluorescence; phenanthrenes; photoelimination; HETEROAROMATIC-COMPOUNDS; OPTICAL-PROPERTIES; C-C; B-N; BORON; FLUORESCENCE; POLYMERS;

D O I：

10.1002/anie.201300873

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Highly fluorescent π-conjugated polycyclic azaborines can be prepared from B,N-heterocyclic compounds with a BR2-CH2 unit through the elimination of an R-H molecule (see scheme). These clean photoelimination reactions occur both in solution and in polymers doped with the precursors. Copyright © 2013 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：4544 / 4548

页数：5

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