Luminescent polyoxotungstoeuropate anion-pillared layered double hydroxides

被引：52

作者：

Sousa, FL

Pillinger, M

Ferreira, RAS

Granadeiro, CM

Cavaleiro, AMV

Rocha, J

Carlos, LD

Trindade, T

Nogueira, HIS ^{[1
]}

机构：

[1] Univ Aveiro, CICECO, Dept Chem, P-3810193 Aveiro, Portugal

[2] Univ Aveiro, CICECO, Dept Phys, P-3810193 Aveiro, Portugal

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 04期

关键词：

layered double hydroxides; layered compounds; polyoxometalates; host-guest systems; luminescence;

D O I：

10.1002/ejic.200500518

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Novel luminescent polyoxometalate anion-pillared layered double hydroxides (LDHs) were prepared by aqueous ion exchange of a Zn-A LDH precursor in nitrate form with the europium-containing polyoxotungstate anions [EuW10O36](9-), [Eu(BW11O39)(H2O)(3)](6-) and [Eu(PW11O39)(2)](11-). The hostguest interaction has a strong influence on the nature of the final intercalated species, as evidenced by elemental analysis, powder X-ray diffraction (XRD), infra-red (IR) and Raman spectroscopy, solid state magic-angle spinning (MAS) B-11 and P-31 NMR spectroscopy, and photoluminescence spectroscopy. (c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006.

引用

页码：726 / 734

页数：9

共 50 条

[1] Formation of organic anion-pillared layered zinc hydroxides by coprecipitation
Takahashi, S
Iwasa, T
Kanazawa, Y
Umetsu, Y
Narita, E
NIPPON KAGAKU KAISHI, 1997, (07) : 502 - 507
[2] Structural studies of polyoxometalate-anion-pillared layered double hydroxides
Evans, J
Pillinger, M
Zhang, JJ
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1996, (14): : 2963 - 2974
[3] Layered double hydroxides pillared by macropolyoxometalates
Dept. Chem. Ctr. Fundamental Mat. R., East Lansing, MI 48824, United States
Appl. Clay Sci., 5-6 (479-494):
[4] Layered double hydroxides pillared by macropolyoxometalates
Gardner, EA
Yun, SK
Kwon, TH
Pinnavaia, TJ
APPLIED CLAY SCIENCE, 1998, 13 (5-6) : 479 - 494
[5] Theoretical evaluation of the microporosity of pillared layered double hydroxides
Nijs, H
De Bock, M
Maes, N
Vansant, EF
JOURNAL OF POROUS MATERIALS, 1999, 6 (04) : 307 - 321
[6] Synthesis and characterization of layered double hydroxides pillared with peroxoheteropolyanions
Hua, Rui-Nian
Shan, Qiu-Jie
Gong, Jian
Qu, Lun-Yu
Kao Teng Hsueh Hsiao Hua Heush Hsueh Pao/ Chemical Journal of Chinese Universities, 1996, 17 (10):
[7] Theoretical Evaluation of the Microporosity of Pillared Layered Double Hydroxides
H. Nijs
M. De Bock
N. Maes
E.F. Vansant
Journal of Porous Materials, 1999, 6 : 307 - 321
[8] Synthesis and characterization of layered double hydroxides pillared with peroxoheteropolyanions
Hua, RN
Shan, QJ
Gong, JA
Qu, LY
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 1996, 17 (10): : 1500 - 1503
[9] SYNTHETIC AND CATALYTIC STUDIES OF INORGANICALLY PILLARED AND ORGANICALLY PILLARED LAYERED DOUBLE HYDROXIDES
WANG, JD
SERRETTE, G
TIAN, Y
CLEARFIELD, A
APPLIED CLAY SCIENCE, 1995, 10 (1-2) : 103 - 115
[10] LAYERED DOUBLE HYDROXIDES FOR ANION CAPTURE AND STORAGE
Phillips, J.
Vandeperre, L. J.
CERAMIC MATERIALS FOR ENERGY APPLICATIONS, 2011, 32 (09): : 33 - 39

← 1 2 3 4 5 →