Copper Iron Conversion Coating for Solid Oxide Fuel Cell Interconnects

被引:33
|
作者
Grolig, Jan Gustav [1 ]
Alnegren, Patrik [1 ]
Froitzheim, Jan [1 ]
Svensson, Jan-Erik [1 ]
机构
[1] Chalmers, Environm Inorgan Chem, SE-41296 Gothenburg, Sweden
基金
瑞典研究理事会;
关键词
Interconnect; Corrosion; Chromium volatilization; Sanergy HT; SOFC; Area specific resistance; FERRITIC STAINLESS-STEEL; SOFC INTERCONNECTS; CHROMIUM VAPORIZATION; SPINEL COATINGS; ELECTRICAL-CONDUCTIVITY; METALLIC INTERCONNECTS; OXIDATION PERFORMANCE; CO; BEHAVIOR; COBALT;
D O I
10.1016/j.jpowsour.2015.06.139
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A conversion coating of iron and copper was investigated with the purpose of increasing the performance of Sanergy HT as a potential SOFC interconnect material. Samples were exposed to a simulated cathode atmosphere (air, 3 % H2O) for durations of up to 1000 h at 850 degrees C. Their performance in terms of corrosion, chromium evaporation and electrical resistance (ASR) was monitored and compared to uncoated and cobalt-coated Sanergy HT samples. The copper iron coating had no negative effects on corrosion protection and decreased chromium evaporation by about 80%. An Area Specific Resistance (ASR) of 10 m Omega cm(2) was reached after 1000 h of exposure. Scanning Electron Microscopy revealed well adherent oxide layers comprised of an inner chromia layer and an outer spinel oxide layer. (C) 2015 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license
引用
收藏
页码:534 / 539
页数:6
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