Ancillary Metal Centers in Frustrated Lewis Pair Chemistry: Ruthenium Acetylide as a Lewis Base in the Activation of CO2, Aldehyde, and Alkyne

被引：30
|
作者：
Boone, Michael P. [1 ]
Stephan, Douglas W. [1 ]
机构：
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
来源：
ORGANOMETALLICS | 2014年 / 33卷 / 01期
基金：
加拿大自然科学与工程研究理事会;
关键词：
CYCLOPENTADIENYL-OSMIUM CHEMISTRY; ZIRCONOCENE-PHOSPHINOARYLOXIDE COMPLEXES; FUNCTIONAL-GROUP CHEMISTRY; FREE HYDROGEN ACTIVATION; ELECTRON-POOR ALLENES; X-RAY STRUCTURES; VINYLIDENE REARRANGEMENTS; ADDITION-REACTIONS; ROOM-TEMPERATURE; SMALL MOLECULES;
D O I：
10.1021/om401118n
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The combination of (indenyl)Ru(PPh3)(2)(CCPh) (1) with B(C6F4H)(3) or Al(C6F5)(3) generates FLPs that are shown to react with CO2, aldehyde, and alkyne to generated new C-C bonds. While in these reactions the metal center is ancillary, subsequent reaction of the alkyne addition product with additional alkyne prompts Ru vinylidene chemistry that releases the new organic fragment from Ru.
引用
收藏
页码：387 / 393
页数：7
相关论文
共 50 条
  • [1] Frustrated Lewis pair chemistry of CO
    Stephan, Douglas W. W.
    CHEMICAL SOCIETY REVIEWS, 2023, 52 (14) : 4632 - 4643
  • [2] CO2 activation employing a silylium-phosphine frustrated Lewis pair
    Hunt, Patricia
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 253
  • [3] Frustrated Lewis Pair Catalyzed Hydrogenation of Amides: Halides as Active Lewis Base in the Metal-Free Hydrogen Activation
    Sitte, Nikolai A.
    Bursch, Markus
    Grimme, Stefan
    Paradies, Jan
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (01) : 159 - 162
  • [4] Design of Frustrated Lewis Pair Catalysts for Direct Hydrogenation of CO2
    Das, Shubhajit
    Turnell-Ritson, Roland C.
    Dyson, Paul J.
    Corminboeuf, Clemence
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (46)
  • [5] Roles of the Lewis acid and base in the chemical reduction of CO2 catalyzed by frustrated Lewis pairs
    Lim, Chern-Hooi
    Holder, Aaron M.
    Hynes, James T.
    Musgrave, Charles B.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2014, 248
  • [6] Roles of the Lewis Acid and Base in the Chemical Reduction of CO2 Catalyzed by Frustrated Lewis Pairs
    Lim, Chern-Hooi
    Holder, Aaron M.
    Hynes, James T.
    Musgrave, Charles B.
    INORGANIC CHEMISTRY, 2013, 52 (17) : 10062 - 10066
  • [7] Developing carbon Lewis base/boron Lewis acid frustrated Lewis pair chemistry derived from conjugated dienamines
    Moericke, Jennifer
    Rehwinkel, Florian
    Danelzik, Tobias
    Daniliuc, Constantin G.
    Wibbeling, Birgit
    Kehr, Gerald
    Erker, Gerhard
    TETRAHEDRON, 2019, 75 (05) : 571 - 579
  • [8] Frustrated Lewis Pair Chemistry Meets Metal-Organic Frameworks
    Stephan, Douglas W.
    CHEM, 2018, 4 (11): : 2483 - 2485
  • [9] Implications of CO2 Activation by Frustrated Lewis Pairs in the Catalytic Hydroboration of CO2: A View Using N/Si+ Frustrated Lewis Pairs
    von Wolff, N.
    Lefevre, G.
    Berthet, J. -C.
    Thuery, P.
    Cantat, T.
    ACS CATALYSIS, 2016, 6 (07): : 4526 - 4535
  • [10] Zero valent iron complexes as base partners in frustrated Lewis pair chemistry
    Tinnermann, Hendrik
    Fraser, Craig
    Young, Rowan D.
    DALTON TRANSACTIONS, 2020, 49 (43) : 15184 - 15189
12345