Influence of water vapor on the response of Mg-doped SrTiO3 ceramic oxygen sensors

Mg-doped SrTiO3 thick film sensors fabricated by screen-printing proved to be very promising for the use as oxygen sensors. A study of the influence of water on the response of these sensors gives an important basis for understanding their behavior in practical applications. The influence of water on the sensor response was measured in the oxygen partial pressure region from air (0.21 bar) to pure N-2 (2.5 x 10(-5) bar) and the temperature range from 600 to 800 degrees C. The relative humidity was varied from 1 to 95% RH. The resistance variation as a function of temperature and the activation energy were evaluated under different dry and wet conditions. The results obtained show that the resistance of these sensors generally decreases with increasing water content in the carrier gas and that the effect of water was strongest at lower temperatures as well as at lower oxygen pressures. To explain this behavior, it is proposed that a partial proton conduction is introduced in the water-containing atmospheres and that this contributes to the total conductivity leading to a reduction of the total resistance. Finally, the measurements also show that the response of these sensors still depends on the oxygen partial pressure according to the standard expression even in the presence of water vapor. Therefore, these sensors can still be used as oxygen sensors in humid atmospheres.