Enhanced ferroelectric properties and thermal stability of nonstoichiometric 0.92(Na0.5Bi0.5)TiO3-0.08(K0.5Bi0.5)TiO3 single crystals

被引：25
|
作者：
Zhang, Haiwu [1 ,2 ]
Chen, Chao [1 ,2 ]
Zhao, Xiangyong [1 ]
Deng, Hao [1 ,2 ]
Li, Long [1 ,2 ]
Lin, Di [1 ]
Li, Xiaobing [1 ]
Ren, Bo [1 ]
Luo, Haosu [1 ]
Yan, Jun [3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Ceram, Key Lab Inorgan Funct Mat & Devices, Shanghai 201800, Peoples R China
[2] Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China
[3] Shanghai Municipal Elect Power Co, Shibei Power Supply Branch, Shanghai 200072, Peoples R China
来源：
APPLIED PHYSICS LETTERS | 2013年 / 103卷 / 21期
关键词：
TRANSMISSION ELECTRON-MICROSCOPY; PIEZOELECTRIC PROPERTIES; NA0.5BI0.5TIO3; CERAMICS; GROWTH;
D O I：
10.1063/1.4833401
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
Bi deficient, Mn doped 0.92(Na0.5Bi0.5) TiO3-0.08(K0.5Bi0.5)TiO3 single crystals were grown by carefully controlled top-seeded solution growth method. Local structures were investigated by transmission electron microscopy. The site occupation and valence state of manganese were characterized by electron paramagnetic resonance spectrum. The leakage current density in the as-grown single crystals is effectively depressed. The introduced defect complexes suppress the temperature induced phase transformation, increasing the depolarization temperature (165 degrees C) and thermal stability of ferroelectric properties. (C) 2013 AIP Publishing LLC.
引用
收藏
页数：5
相关论文
共 50 条
  • [1] Flux growth of lead free (Na0.5Bi0.5)TiO3-(K0.5Bi0.5)TiO3 ferroelectric single crystals and their characterization
    Bhandari, Sonia
    Sinha, Nidhi
    Ray, Geeta
    Kumar, Binay
    CRYSTENGCOMM, 2014, 16 (21): : 4459 - 4466
  • [2] Synthesis of (Na0.5Bi0.5)TiO3 and (Na0.5Bi0.5)0.92Ba0.08TiO3 powders by a citrate method
    Qing Xu
    Shutao Chen
    Wen Chen
    Duanping Huang
    Jing Zhou
    Huajun Sun
    Yueming Li
    Journal of Materials Science, 2006, 41 : 6146 - 6149
  • [3] Synthesis of (Na0.5Bi0.5)TiO3 and (Na0.5Bi0.5)0.92Ba0.08TiO3 powders by a citrate method
    Xu, Qing
    Chen, Shutao
    Chen, Wen
    Huang, Duanping
    Zhou, Jing
    Sun, Huajun
    Li, Yueming
    JOURNAL OF MATERIALS SCIENCE, 2006, 41 (18) : 6146 - 6149
  • [4] PYROELECTRIC PROPERTIES OF SOLID-SOLUTIONS (NA0.5BI0.5) TIO3-(K0.5BI0.5)TIO3
    GADZHIEV, MS
    ABIEV, AK
    ISUPOV, VA
    ISMAILZADE, IG
    FIZIKA TVERDOGO TELA, 1985, 27 (08): : 2507 - 2508
  • [5] ENHANCED PIEZOELECTRIC PROPERTIES IN (Bi0.5K0.5)TiO3-(Bi0.5Na0.5)TiO3 FERROELECTRIC SINGLE CRYSTALS
    Morishita, Akifumi
    Kitanaka, Yuuki
    Izumi, Makoto
    Noguchi, Yuji
    Miyayama, Masaru
    JOURNAL OF ADVANCED DIELECTRICS, 2011, 1 (01) : 63 - 69
  • [6] Structure and ferroelectricity of nonstoichiometric (Na0.5Bi0.5)TiO3
    Carter, Jared
    Aksel, Elena
    Iamsasri, Thanakorn
    Forrester, Jennifer S.
    Chen, Jun
    Jones, Jacob L.
    APPLIED PHYSICS LETTERS, 2014, 104 (11)
  • [7] Crystal growth and ferroelectric properties in Bi0.5K0.5TiO3-Bi0.5Na0.5TiO3 crystals
    Morishita, Akifumi
    Kitanaka, Yuuki
    Izumi, Makoto
    Noguchi, Yuji
    Miyayama, Masaru
    ELECTROCERAMICS IN JAPAN XIII, 2010, 445 : 7 - 10
  • [8] Enhanced dielectric and piezoelectric properties of Ta-doped 0.50 (Na0.5Bi0.5)TiO3-0.50(K0.5Bi0.5)TiO3 lead-free ferroelectric ceramics
    Kumar, Krishan
    Sinha, Nidhi
    Bhandari, Sonia
    Kumar, Binay
    CERAMICS INTERNATIONAL, 2015, 41 (08) : 10237 - 10242
  • [9] Effect of Mn doping on dielectric and piezoelectric properties of (Na0.5Bi0.5)TiO3-0.1BaTiO3-0.1(K0.5Bi0.5)TiO3 ceramics
    Chen Jianhua
    Qu Shaobo
    Gao Kunhua
    Pei Zhibin
    Zhu Linhu
    RARE METAL MATERIALS AND ENGINEERING, 2006, 35 (11) : 1704 - 1707
  • [10] Piezoelectric properties in (K0.5Bi0.5)TiO3-(Na0.5Bi0.5)TiO3-BaTiO3 lead-free ceramics
    Zhang, Shujun
    Shrout, Thomas R.
    Nagata, Hajime
    Hiruma, Yuji
    Takenaka, Tadashi
    IEEE TRANSACTIONS ON ULTRASONICS FERROELECTRICS AND FREQUENCY CONTROL, 2007, 54 (05) : 910 - 917
12345