Continuous Flow Organocatalytic C-H Functionalization and Cross-Dehydrogenative Coupling Reactions: Visible Light Organophotocatalysis for Multicomponent Reactions and C-C, C-P Bond Formations

被引:181
|
作者
Rueping, Magnus [1 ]
Vila, Carlos [1 ]
Bootwicha, Teerawut [1 ]
机构
[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52074 Aachen, Germany
来源
ACS CATALYSIS | 2013年 / 3卷 / 07期
关键词
Photocatalysis; Sustainable Catalysis; Organocatalysis; Photoreactor; Rose Bengal; PHOTOREDOX CATALYSIS; AEROBIC OXIDATION; FORMING REACTIONS; AMINO RADICALS; DUAL CATALYSIS; ROSE-BENGAL; PHOTOCATALYSIS; CYCLOADDITIONS; EFFICIENT; ACIDS;
D O I
10.1021/cs400350j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A continuous flow procedure for the efficient metal-free, visible light photoredox-catalyzed alpha-functionalization of tertiary amines has been developed. Rose Bengal has been identified as an effective organic photocatalyst for continuous flow C-C and C-P bond formations as well as multicomponent reactions.
引用
收藏
页码:1676 / 1680
页数:5
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