Thermodynamic measurement of Dy+Fe binary system by double Knudsen cell mass spectrometry

被引：10
|
作者：
Nagai, Takashi [1 ]
Shirai, Sho [2 ]
Maeda, Masafumi [2 ]
机构：
[1] Chiba Inst Technol, Dept Mech Sci & Engn, Narashino, Chiba 2750016, Japan
[2] Univ Tokyo, Inst Ind Sci, Meguro Ku, Tokyo 1538505, Japan
来源：
JOURNAL OF CHEMICAL THERMODYNAMICS | 2013年 / 65卷
关键词：
Thermodynamics; Activity; Gibbs energy; Mass spectrometry; FE;
D O I：
10.1016/j.jct.2013.05.034
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The activities of Dy in Dy-Fe alloys with Dy concentrations ranging from (7.0 to 89) at% were determined at (1273 to 1573) K by measuring the ion current of the vapor of Dy in equilibrium with Dy-Fe melts, Dy2Fe17 + gamma Fe, etc. The standard Gibbs energy of formation of Dy2Fe17, Dy6Fe23, DyFe3, and DyFe2 were calculated from the activities of Dy obtained from these measurements. Crown Copyright (c) 2013 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码：78 / 82
页数：5
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