Syntheses and Crystal Structures of Two Copper Complexes with Pyridyl-Substituted Phenol Ligand

被引：4

作者：

Gao Da-Zhi ^{[1
]}

Wang Ruo-Xu ^{[1
]}

Ye Fan ^{[1
]}

Shen Xuan ^{[1
]}

Xu Yan ^{[1
]}

Zhu Dun-Ru ^{[1
]}

机构：

[1] Nanjing Univ Technol, Coll Chem & Chem Engn, State Key Lab Mat Oriented Chem Engn, Nanjing 210009, Jiangsu, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2013年 / 29卷 / 11期

关键词：

phenol ligand; Cu(II) complex; crystal structure; ACTIVE-SITES; PURPLE; RELEVANCE; MODELS;

D O I：

10.3969/j.issn.1001-4861.2013.00.384

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two mononuclear copper(II) complexes, [CuL(CH3CN)(ClO4)]ClO4(1) and cis-[CuL(NCS)(2)]center dot 0.5C(4)H(8)O(2)(2) (L=2-[N,N-di (2-pyridylmethyl)aminomethyl]-6-aldehydo-4-methylphenol) have been synthesized and characterized by UV-Vis, FTIR, ESI-MS, elemental analysis and single crystal X-ray crystallography. Both 1 and 2 crystallize in a monoclinic system. Each copper(II) ion locates in a distorted octahedron geometry. As a tetradentate chelating ligand, the L coordinates to copper(II) ion via two pyridyl N atoms, one N atom of tertiary amine, and one phenol O atom. In 1, an acetonitrile molecule and a perchlorate anion also take part in coordination; while there are two cis-disposed NCS- ions in 2. CCDC: 938954, 1; 938955, 2.

引用

页码：2438 / 2444

页数：7

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