Photocatalytic activity of metal ion (Fe or W) doped titania

被引：16
|
作者：
Lee, SS [1 ]
Kim, HJ [1 ]
Jung, KT [1 ]
Kim, HS [1 ]
Shul, YG [1 ]
机构：
[1] Yonsei Univ, Dept Chem Engn, Seoul 120749, South Korea
来源：
KOREAN JOURNAL OF CHEMICAL ENGINEERING | 2001年 / 18卷 / 06期
关键词：
photocatalysis; photocatalyst; TiO2; metal-doped TiO2;
D O I：
10.1007/BF02705618
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Iron or tungsten-doped nano TiO2 were successfully synthesized from TiCl4. All of the samples showed anatase phase of TiO2. For the iron-doped TiO2, Iron ion was well dispersed in the TiO2 lattice. However, tungsten-doped TiO2 formed 12-tungstate with anatase TiO2. As the concentration of tungsten increased, 12-tungstate disappeared. The photocatalytic oxidation of acetaldehyde was evaluated to examine the photocatalytic characteristics of metal-doped TiO2. Because of the surface containing metal oxide or metal precursors at high concentration metal ion, increasing the concentration of W or Fe ion decreased the reactivity. The reaction rate was drastically increased after 300 degreesC heat treatment. Furthermore, the photocatalytic activity of iron- or tungsten-doped TiO2 was higher than that of synthesized pure TiO2 and commercial TiO2.
引用
收藏
页码：914 / 918
页数：5
相关论文
共 50 条
  • [1] Photocatalytic activity of metal ion (Fe or W) doped titania
    Sang Soo Lee
    Hyun Jong Kim
    Kyung Taek Jung
    Hak Soo Kim
    Yong Gun Shul
    Korean Journal of Chemical Engineering, 2001, 18 : 914 - 918
  • [2] Preparation of Metal Ion Doped Titania Nanowires and Their Visible Light Photocatalytic Activity
    Liu Xiangzhi
    Xu Mingxia
    Li Shun
    Zhang Nianxing
    RARE METAL MATERIALS AND ENGINEERING, 2008, 37 : 391 - 394
  • [3] Visible-Light Excitated Photocatalytic Activity of Rare Earth Metal-Ion-Doped Titania
    谢一兵
    李萍
    袁春伟
    Journal of Rare Earths, 2002, (06) : 619 - 625
  • [4] Synthesis, characterization and photocatalytic activity of alkaline earth metal doped titania
    Avasarala, Balaram Kiran
    Tirukkovalluri, Siva Rao
    Bojja, Sreedhar
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2010, 49 (09): : 1189 - 1196
  • [5] Effects of Calcining Temperature on Photocatalytic Activity of Fe-Doped Sulfated Titania
    Yang, Ying
    Tian, Congxue
    PHOTOCHEMISTRY AND PHOTOBIOLOGY, 2012, 88 (04) : 816 - 823
  • [6] Synthesis, characterization and photocatalytic activity of different metal-doped titania systems
    Colmenares, J. C.
    Aramendia, M. A.
    Marinas, A.
    Marinas, J. M.
    Urbano, F. J.
    APPLIED CATALYSIS A-GENERAL, 2006, 306 (120-127) : 120 - 127
  • [7] Performance of a Metal Ion-Doped Titania-Coated Planar Photocatalytic Microreactor
    Lin, Cheng
    Liu, Mingyan
    Yang, Zhongguo
    CHEMICAL ENGINEERING & TECHNOLOGY, 2016, 39 (01) : 88 - 96
  • [8] Evaluating the potential of a new titania precursor for the synthesis of mesoporous Fe-doped titania with enhanced photocatalytic activity
    Goswami, Pallabi
    Ganguli, Jatindra Nath
    MATERIALS RESEARCH BULLETIN, 2012, 47 (08) : 2077 - 2084
  • [9] Photocatalytic Activity of Fe-Doped Titania Hollow Spheres Prepared by Hydrothermal Precipitation
    Kuang Jidong
    Lin Bizhou
    Chen Yilin
    Pian Xuetao
    Zhang Kezhi
    Zhang Ou
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (11) : 1399 - 1404
  • [10] Promotion of photocatalytic activity of Titania by the combination with nitrogen-doped Titania
    Liu, Bin
    Yin, Shu
    Li, Ruixing
    Wang, Yuhua
    Sato, Tsugio
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2007, 115 (1347) : 692 - 696
12345