New skeletal 3D polymeric inorganic cluster [W4S16Cu16Cl16]n with Cu in mixed-valence states:: Solid-state synthesis, crystal structure, and third-order nonlinear optical properties

被引：51
|
作者：
Cai, Y
Wang, Y
Li, YZ
Wang, XS
Xin, XQ
Liu, CM
Zheng, HG [1 ]
机构：
[1] Nanjing Univ, State Key Lab Coordinat Chem, Inst Coordinat Chem, Nanjing 210093, Peoples R China
[2] Nanjing Univ, Ctr Mat Anal, Nanjing 210093, Peoples R China
[3] Jiangsu Teachers Univ Technol, Prov Key Lab Precious Met Chem, Changzhou 213001, Peoples R China
[4] Chinese Acad Sci, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China
来源：
INORGANIC CHEMISTRY | 2005年 / 44卷 / 25期
关键词：
D O I：
10.1021/ic051230n
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new 3D polymeric inorganic cluster with Cu in mixed-valence states was synthesized by the solid-state reaction of (NH4)(2)WS4, S-8, CuCl, and Et4NCl; S8 may be regarded as the oxidizing agent converting Cu(I) to Cu(II) and causing the polymerization of [WS4](2-). The third-order nonlinear optical (NLO) properties are determined, and the results show that the cluster exhibits both large NLO absorptive and strong refractive behaviors.
引用
收藏
页码：9128 / 9130
页数：3
相关论文
共 5 条
  • [1] Studies on the solid-state synthesis and the third-order nonlinear optical properties of the Mo(W)/S/Cu(Ag) cluster compounds
    Zhang, C
    Jin, GC
    Xin, XQ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2000, 16 (02) : 229 - 240
  • [2] SOLID-STATE SYNTHESIS, CRYSTAL-STRUCTURE, AND NONLINEAR REFRACTIVE AND ABSORPTIVE PROPERTIES OF THE NEW CLUSTER (N-BU(4)N)(2)[MOOS3CU3BRCL2]
    HOU, HW
    YE, XG
    XIN, XQ
    LIU, J
    CHEN, MQ
    SHI, S
    CHEMISTRY OF MATERIALS, 1995, 7 (03) : 472 - 476
  • [3] Synthesis, crystal structure and third-order nonlinear optical properties of heterometallic cluster [WM2S4(Pph3)3]•DMF (M2=1.25Ag+0.75Cu)
    Zhang, Zhao-Xia
    Li, Yong
    Li, Ke-Chang
    Song, Wen-Dong
    Li, Qiu-Shun
    Xiong, Hao-Ping
    Xu, Ji-Qing
    Pan, Ling-Yun
    JOURNAL OF MOLECULAR STRUCTURE, 2006, 791 (1-3) : 117 - 121
  • [4] Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS3Cu2 (4-tBuPy)2]2 (4-tBuPy=4-tert-butylpyridine)
    Wu, Bing
    Zhang, Wen-Hua
    Li, Hong-Xi
    Ren, Zhi-Gang
    Lang, Han-Ping
    Zhang, Yong
    Song, Ying-Lin
    JOURNAL OF MOLECULAR STRUCTURE, 2007, 829 (1-3) : 128 - 134
  • [5] SOLID-STATE SYNTHESIS, CRYSTAL-STRUCTURE, AND EFFECTIVE 3RD-ORDER NONLINEAR-OPTICAL PROPERTIES OF (NET(4))(3)[MOOS3CU3BR3(MU(2)-BR)]CENTER-DOT-2H(2)O
    SHI, S
    CHEN, ZR
    HOU, HW
    XIN, XQ
    YU, KB
    CHEMISTRY OF MATERIALS, 1995, 7 (08) : 1519 - 1524
1