PPy modified titanium foam electrode with high performance for supercapacitor

被引:26
|
作者
Wei, Jiatong [1 ]
Wei, Susheng [2 ]
Wang, Guibao [1 ]
He, Xinping [1 ]
Gao, Bo [3 ]
Zhao, Chun [1 ]
机构
[1] Jilin Univ, State Key Lab Integrated Optoelect, Coll Elect Sci & Engn, Changchun 130012, Peoples R China
[2] Chinese Acad Sci, Changchun Inst Opt Fine Mech & Phys, Changchun 130033, Peoples R China
[3] Jilin Agr Univ, Dept Resources & Environm, Changchun 130018, Peoples R China
关键词
Polypyrrole; Titanium foam; Supercapacitor; High specific capacitance; ELECTROCHEMICAL SUPERCAPACITOR; NICKEL FOAM; POLYPYRROLE; COMPOSITE; NANOCOMPOSITES;
D O I
10.1016/j.eurpolymj.2013.08.001
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Pyrrole was polymerized on the surface of titanium foam using FeCl3 as oxidant and the as-synthesized product could be directly used as electrode for supercapacitor. The globular polypyrrole (PPy) particles were firmly loaded on the substrate with high density. The morphology study of PPy film is observed in SEM images, the XRD, FTIR and UV-vis spectra reveal the structure and crystalline of PPy nanoparticles. The electrochemical properties of PPy modified electrode are investigated by cyclic voltammetry (CV), galvanostatic charge/discharge (GCD) and cycle life techniques. The electrochemical measurements showed such a PPy-Ti electrode had a wide working potential window, a high specific capacitance of 855 F g(-1) and excellent cycle stability at a discharge current density of 1 A g(-1). (C) 2013 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3651 / 3656
页数:6
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