Epoxidation of alkenes by a readily prepared and highly active and reusable heterogeneous molybdenum-based catalyst

被引：54
|
作者：
Grivani, G
Tangestaninejad, S [1 ]
Habibi, MH
Mirkhani, V
Moghadam, M
机构：
[1] Isfahan Univ, Dept Chem, Esfahan 81746, Iran
[2] Univ Yasuj, Dept Chem, Yasuj 75914, Iran
来源：
APPLIED CATALYSIS A-GENERAL | 2006年 / 299卷
关键词：
molybdenum carbonyl; heterogeneous catalyst; epoxidation; tert-butylhydroperoxide;
D O I：
10.1016/j.apcata.2005.10.032
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Polymer-bound piperazine was readily prepared from Merrifield resin and was used as a robust support for immobilization of molybdenum hexacarbonyl. This polymer-supported molybdenum catalyst shows high activity in the epoxidation of various alkenes in the presence of tertbutylhydroperoxide (TBHP). This new heterogenized molybdenum catalyst can be recovered and reused for eight times without loss of its activity. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码：131 / 136
页数：6
相关论文
共 50 条
  • [1] Readily prepared heterogeneous molybdenum-based catalysts as highly recoverable, reusable and active catalysts for alkene epoxidation
    Tangestaninejad, Shahram
    Mirkhani, Valiollah
    Moghadam, Majid
    Grivani, Gholamhossein
    CATALYSIS COMMUNICATIONS, 2007, 8 (05) : 839 - 844
  • [2] A readily prepared, highly reusable and active polymer-supported molybdenum carbonyl Schiff base complex as epoxidation catalyst
    Grivani, Gholamhossein
    Tangestaninejad, Shahram
    Halili, Akbar
    INORGANIC CHEMISTRY COMMUNICATIONS, 2007, 10 (08) : 914 - 917
  • [3] Readily prepared polymer-supported molybdenum carbonyls as novel reusable and highly active epoxidation catalysts
    Tangestaninejad, Shahram
    Habibi, Mohammad Hossein
    Mirkhani, Valiollah
    Moghadam, Majid
    Grivani, Gholamhossein
    INORGANIC CHEMISTRY COMMUNICATIONS, 2006, 9 (06) : 575 - 578
  • [4] Epoxidation of alkenes by a highly reusable and efficient polymer-supported molybdenum carbonyl catalyst
    Grivani, G
    Tangestaninejad, S
    Habibi, MH
    Mirkhani, V
    CATALYSIS COMMUNICATIONS, 2005, 6 (06) : 375 - 378
  • [5] Recent Progress in Application of Molybdenum-Based Catalysts for Epoxidation of Alkenes
    Shen, Yirui
    Jiang, Pingping
    Wai, Phyu Thin
    Gu, Qian
    Zhang, Weijie
    CATALYSTS, 2019, 9 (01)
  • [6] Low-Valent Molybdenum-Based Dual Pre-Catalysts for Highly Efficient Catalytic Epoxidation of Alkenes and Deoxygenation of Sulfoxides
    Krackl, Sebastian
    Company, Anna
    Enthaler, Stephan
    Driess, Matthias
    CHEMCATCHEM, 2011, 3 (07) : 1186 - 1192
  • [7] A highly active and reusable heterogeneous ruthenium catalyst for olefin metathesis
    Li, L
    Shi, JL
    ADVANCED SYNTHESIS & CATALYSIS, 2005, 347 (14) : 1745 - 1749
  • [8] Multi-wall carbon nanotubes supported molybdenum hexacarbonyl: An efficient and highly reusable catalyst for epoxidation of alkenes with tert-butyl hydroperoxide
    Moghadam, Majid
    Tangestaninejad, Shahram
    Mirkhani, Valiollah
    Mohammadpoor-Baltork, Iraj
    Mirjafari, Arsalan
    Mirbagheri, Naghmeh Sadat
    JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2010, 329 (1-2) : 44 - 49
  • [9] Immobilization of molybdenum-based complexes on dendrimer-functionalized graphene oxide and their catalytic activity for the epoxidation of alkenes
    Fan, Zhanfang
    Lin, Bin
    Liu, Yongqing
    Liu, Yang
    Cheng, Maosheng
    CATALYSIS COMMUNICATIONS, 2021, 158
  • [10] Molybdenum-Based Polyoxometalates as Highly Active and Selective Catalysts for the Epimerization of Aldoses
    Ju, Feifei
    VanderVelde, David
    Nikolla, Eranda
    ACS CATALYSIS, 2014, 4 (05): : 1358 - 1364
12345