The catalytic system tri-n-butyl boron-p-quinone in the free-radical polymerization of styrene

被引：16
|
作者：
Kuznetsova, Yu. L. [1 ]
Chesnokov, S. A. [2 ]
Zaitsev, S. D. [1 ]
Ludin, D. V. [1 ]
机构：
[1] Nizhnii Novgorod State Univ, Nizhnii Novgorod 603950, Russia
[2] Russian Acad Sci, Razuvaev Inst Organometall Chem, Nizhnii Novgorod 603950, Russia
来源：
POLYMER SCIENCE SERIES B | 2012年 / 54卷 / 9-10期
关键词：
METHYL-METHACRYLATE;
D O I：
10.1134/S1560090412090035
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The AIBN-initiated polymerization of styrene is conducted at 60 and 80A degrees C in the presence of tri-n-butyl boron and several p-quinones. The rate of polymerization and the molecular-mass characteristics of the polymers depend on the structure of the used p-quinone and the temperature of the process.
引用
收藏
页码：434 / 442
页数：9
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