Retrograde alterations of phyllosilicates in low-grade metapelite: a case study from the Szendro Paleozoic, NE-Hungary

Frequently, at temperatures lower than the metamorphic peak conditions, slates undergo mineral transformations, usually mediated by fluids. We have studied core material of an epizonal slate series (Szendro Mountains, NE-Hungary) to reconstruct the post-metamorphic lower-T hydrothermal alterations using petrographic, X-ray diffraction, electron microprobe methods, and transmission electron microscopy. The borehole crosscuts an upper part of the ca. 600-800 m Lower-Carboniferous flysch-like Szendro Phyllite Formation. The samples were metamorphosed reaching epizonal conditions with a mineral assemblage characterized by quartz, muscovite, chlorite and albite. Even in the freshest samples, break-up and loosening of the regional metamorphic structure was observed, with cracks parallel to or crossing the cleavage. In the upper part, chlorite and albite are almost absent, while the presence of paragonite, mixed Na-K mica, and mixed-layered minerals with smectitic component are characteristic. Goethite, halloysite, and subordinate kaolinite are present in the most altered sample (13.0 m in the profile) which may indicate the position of the fissures in which the circulation of the post-metamorphic fluids was the most intense. Muscovite is the only mica from the lower part of the profile and chlorite becomes a significant constituent, whereas paragonite, halloysite, and kaolinite are missing. Discrete smectite is present in all the samples in spite of being incompatible with the prograde evolution of the sequence. The interleaved smectite layers in chlorite and muscovite/chlorite mixed-layers show at the lattice level textural characteristics indicative of a later alteration process. After the metamorphic peak at epizonal conditions, the introduction of hot fluids through the fractures gave rise to the crystallization of Na-K white micas and muscovite/chlorite under anchizonal conditions. In a final stage of the hydrothermal process, the cooling of the circulating fluids favored the formation of halloysite and kaolinite in the areas near to the fissures, smectites in the samples far away from the fractures, and locally, goethite. The Fe2O3 content increasing upwards indicates oxidizing conditions in the late stage of hydrothermal activity and/or eventually, an influence of a younger near-surface weathering.