Synthesis of new cyclic aromatic carbene ligands bearing remote amino groups and their palladium(II) complexes

被引：14

作者：

Sugawara, Shun ^{[1
]}

Kojima, Satoshi ^{[1
]}

Yamamoto, Yohsuke ^{[1
]}

机构：

[1] Hiroshima Univ, Grad Sch Sci, Dept Chem, Higashihiroshima 7398526, Japan

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 78期

关键词：

DIAZO PRECURSORS; CHROMIUM; PROBE;

D O I：

10.1039/c2cc33510g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New cyclic aromatic carbene ligands bearing remote amino groups were developed. The oxidative addition of Pd(0) into the chloride precursors yielded the corresponding Pd(II) complexes whose carbene ligand was demonstrated to have stronger donor ability than classical NHCs.

引用

页码：9735 / 9737

页数：3

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