A simple synthesis of 3β-acetoxy-20-oxomethylpregn-5-ene and 3β-acetoxy-20-hydroxymethylpregn-5-ene

被引：1
|
作者：
Drozdov, FV
Timofeev, VP
Misharin, AY
机构：
[1] Russian Acad Med Sci, Orekhovich Inst Biomed Chem, Moscow 119992, Russia
[2] Russian Acad Sci, VA Engelhardt Mol Biol Inst, Moscow 117984, Russia
来源：
RUSSIAN JOURNAL OF BIOORGANIC CHEMISTRY | 2006年 / 32卷 / 01期
基金：
俄罗斯基础研究基金会;
关键词：
sterols; synthesis;
D O I：
10.1134/S1068162006010122
中图分类号：
Q5 [生物化学]; Q7 [分子生物学];
学科分类号：
071010 ; 081704 ;
摘要：
3 beta-Acetoxy-20-oxomethylpreon-5-ene and 3 beta-acetoxy-20-hydroxymethylpregn-5-ene were synthesized from (22R,23R)-sitost-5-ene-3 beta,22,23-triol in 66% overall yields.
引用
收藏
页码：96 / 98
页数：3
相关论文
共 50 条
  • [1] A simple synthesis of 3β-acetoxy-20-oxomethylpregn-5-ene and 3β-acetoxy-20-hydroxymethylpregn-5-ene
    F. V. Drozdov
    V. P. Timofeev
    A. Yu. Misharin
    Russian Journal of Bioorganic Chemistry, 2006, 32 : 96 - 98
  • [2] 3β-Acetoxy-17-ethylenedioxyandrost-5-ene
    Xu, Ye-Ming
    Tang, Shi-Gui
    Zhou, Yi-Xin
    Liu, Shan
    Guo, Cheng
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O3980 - U2384
  • [3] RELIABLE SYNTHESIS OF 3BETA-ACETOXY-6-NITROCHOLEST-5-ENE
    ROWLAND, AT
    STEROIDS, 1975, 26 (02) : 251 - 254
  • [4] HYDROGENOLYSIS OF STEROID 3BETA-ACETOXY-5-ENE SYSTEMS
    PETTIT, GR
    GREEN, B
    CANADIAN JOURNAL OF CHEMISTRY, 1970, 48 (16): : 2635 - &
  • [5] FLOURINATED STERIODS - SYNTHESIS OF 3BETA-FLOURO-17BETA-ACETOXY-ESTR-5(10)-ENE FROM 3BETA-FLOURO-17B-ACETOXY-ANDROST-5-ENE
    BORGNA, JL
    MOUSSERO.M
    BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1970, (06): : 2210 - &
  • [6] 3-BETA-ACETOXY-17-ALPHA-HYDROPEROXY-16-ALPHA-METHYLPREGN-5-ENE-20-ONE DECOMPOSITION PRODUCTS
    KOLYVANOVA, TS
    BAYUNOVA, VI
    BOGDANOVA, GA
    KULESHOVA, EF
    GRINENKO, GS
    KHIMIKO-FARMATSEVTICHESKII ZHURNAL, 1987, 21 (12): : 1471 - 1475
  • [7] 3β-acetoxy-16β-hydroxypregn-5-ene-20-carboxylic acid 16-lactone (vespertilin acetate)
    Flores-Alamo, Marcos
    Rosiles-Exkiws, Jose A.
    Iglesias-Arteaga, Martin A.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2006, 62 : O3774 - O3775
  • [8] SYNTHESIS AND REACTIONS OF 3-BETA-ACETOXY-20-ETHYNYL-5-PREGNEN-20-OL
    SONDHEIMER, F
    DANIELI, N
    MAZUR, Y
    JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (09): : 1278 - 1280
  • [9] Structure determination of 3β-acetoxy-cholest-5-ene-7-one - a steroid
    Rajnikant, A.A.
    Gupta, V.K.
    Khan, E.H.
    Shafi, S.
    Hashmi, S.
    Kristallografiya, 2002, 47 (01): : 82 - 87
  • [10] Structure determination of 3β-acetoxy-cholest-5-ene-7-one - A steroid
    Rajnikant
    Gupta V.K.
    Khan E.H.
    Shafi S.
    Hashmi S.
    Shafiullah
    Varghese B.
    Dinesh
    Crystallography Reports, 2002, 47 (1) : 75 - 79
12345