Understanding Binary Interactions in Fuel-Cell Catalyst-Layer Inks

被引:11
|
作者
Berlinger, S. A. [1 ,2 ]
McCloskey, B. D. [1 ,2 ]
Weber, A. Z. [2 ]
机构
[1] Univ Calif Berkeley, Dept Chem & Biomol Engn, Berkeley, CA 94720 USA
[2] Lawrence Berkeley Natl Lab, Berkeley, CA 94720 USA
来源
基金
美国国家科学基金会;
关键词
ELECTROPHORETIC MOBILITY; PEMFC ELECTRODES; MIXTURE SOLVENT; NAFION; PERFORMANCE; DISPERSION; FABRICATION; PARTICLES;
D O I
10.1149/08008.0309ecst
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Fuel-cell catalyst layers are made from inks comprised of ionomer, catalyst, and solvent. Ionomer interactions within the ink and how they map to catalyst-layer properties are not well understood. Here we study ink stability over time to elucidate stability windows dictated by solvent dielectric constant. Furthermore, we show how the addition of Nafion affects both the stability and aggregation behavior of the ink.
引用
收藏
页码:309 / 319
页数:11
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