Synthesis and characterization of Schiff base derivatives of bimetallic [Mg(II); Al(III)]-μ-oxoisopropoxide

被引：0
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作者：
Sharma, HK [1 ]
Kapoor, PN
机构：
[1] Kurukshetra Univ, Dept Chem, Kurukshetra 136119, Haryana, India
[2] Univ Delhi, Dept Chem, Delhi 110007, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2004年 / 43卷 / 03期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of bimetallic-mu-oxoisopropoxide [MgO2Al2 (OPri)(4)] with schiff bases (HLL') viz. salicylidene-aniline (HSalan), salicylidene-o-toluidene (HSaltoin) or salicylidene-p-chloroaniline (HSalcan) in the molar ratios 1: 1, 1:2 and 1:3 yields compounds of the type [MgO2Al2(Opr(i))(3) (LL'), [MgO2Al2, (OPri)(2)(LL')(2) and [MgO2Al2(OPri)(LL')(3)] (where LL' is deproptonated Schiff's base) respectively. The schiff base derivatives of bimetallic [Mg(II);Al(III)]-mu-oxoisopi-opoxide have been characterized by elemental analysis, molecular weight measurements, and spectral studies (IR, H-1 NMR Al-27 NMR). A dimeric structure for 1:1 and 1:2 and a monomeric structure for 1:3 schiff base derivatives of bimetallic [Mg(II);Al(III)]-mu-oxoi sopropoxide have been tentatively proposed.
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页码：566 / 568
页数：3
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