Catalytic activity of an iron(III) Schiff base complex bound in a polymer resin

被引：8

作者：

Islam, Sk. Manirul ^{[1
]}

Paul, Sumantra ^{[1
]}

Roy, Anupam Singha ^{[1
]}

Banerjee, Satabdi ^{[2
]}

Ghosh, Kajari ^{[1
]}

Dey, Ram Chandra ^{[1
]}

Santra, S. C. ^{[2
]}

机构：

[1] Univ Kalyani, Dept Chem, Nadia 741235, WB, India

[2] Univ Kalyani, Dept Environm Sci, Nadia 741235, WB, India

来源：

TRANSITION METAL CHEMISTRY | 2013年 / 38卷 / 06期

关键词：

SELECTIVE OXIDATION; ASYMMETRIC OXIDATION; HYDROGEN-PEROXIDE; MOLECULAR-SIEVES; C-H; SULFIDES; IRON; CYCLOHEXENE; ALKANES; SBA-15;

D O I：

10.1007/s11243-013-9736-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

An iron(III)-ferrocene complex and its heterogeneous analogue bound in a polymer resin have been prepared and employed as catalysts for the oxidation of various organic substrates. Characterization of the heterogeneous and homogeneous complexes was done by SEM, EDAX, TGA, FT-IR, DRS-UV, and spectroscopy. The catalyst's activity, stability, and reusability were investigated through industrially relevant oxidation reactions. The solid iron(III)-ferrocene Schiff base complex gave more effective results than the solid-supported ferrocene Schiff base ligand. The antimicrobial activities of the molecular complex and free ligand were studied for Gram-positive and Gram-negative bacteria.

引用

页码：675 / 682

页数：8

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