Thermochemical properties of tert-butyl and cumyl derivatives of peroxide compounds

被引:2
|
作者
Pavlovskii, Yu. P. [1 ]
Kachurina, N. S. [1 ]
Gerasimchuk, S. I. [1 ]
Van-Chin-Syan, Yu. Ya. [1 ]
机构
[1] Lviv Polytech Natl Univ, UA-79013 Lvov, Ukraine
关键词
organic peroxide; calorimetry; bond energy; VAPOR-PRESSURE; VAPORIZATION;
D O I
10.1134/S003602441307025X
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Standard enthalpies of combustion, formation, and vaporization (sublimation) of five organic peroxides have been determined according to calorimetry. Influence of the nature of substituents on the energy of peroxide bond has been established.
引用
收藏
页码:1253 / 1258
页数:6
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