Self-assembly of cyclic peptides into nanotubes and then into highly anisotropic crystalline materials

被引:1
|
作者
Gauthier, D [1 ]
Baillargeon, P [1 ]
Drouin, M [1 ]
Dory, YL [1 ]
机构
[1] Univ Sherbrooke, Dept Chim, Lab Synthese Supramol, Sherbrooke, PQ J1H 5N4, Canada
关键词
lactams; nanotubes; peptides; self-assembly; supramolecular chemistry;
D O I
10.1002/1521-3773(20011217)40:24<4635::AID-ANIE4635>3.0.CO;2-D
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
C3-symmetric lactams in a tube: Specially designed rigid disc-shaped macrolactams self-assemble as endless tubes by means of backbone backbone hydrogen bonds and van der Waals contacts (see scheme). All the tubes with very strong dipoles further aggregate in a parallel fashion and all the dipoles are still oriented in the same direction.
引用
收藏
页码:4635 / +
页数:5
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