Micro/Nano Crystal Composed of Tetrathiafulvalene-Tetracyanoquinodimethane Prepared Using a Charge Transfer-Induced Reprecipitation Method

被引:2
|
作者
Takeda, Masaki [1 ]
Umemoto, Kazuki [1 ]
Nohara, Tomohiro [1 ]
Tozawa, Keitaro [2 ]
Matsui, Jun [3 ]
Masuhara, Akito [1 ,4 ]
机构
[1] Yamagata Univ, Grad Sch Sci & Engn, Yonezawa, Yamagata 9928510, Japan
[2] Yamagata Univ, Fac Engn, Yonezawa, Yamagata 9928510, Japan
[3] Yamagata Univ, Fac Sci, Yamagata, Yamagata 9908560, Japan
[4] Res Ctr Organ Elect ROEL, Yonezawa, Yamagata 9928510, Japan
关键词
ELECTRON-TRANSFER; TTF-TCNQ; CONDUCTION; DESIGN; FILMS;
D O I
10.1149/2.0221909jes
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
In this study, we performed a micro/nanocrystallization of charge transfer crystals (CTCs) composed of tetrathiafulvalene (TTF)-tetracyanoquinodimethane (TCNQ) via a charge transfer-induced reprecipitation method. Depending on the order of injected solution, TTF-TCNQ CTCs formed a nanorod or a nanorod-coated rhombic shape. We concluded that the crystallinity of the TCNQ particles in the water dispersion determines the final CTC shape. (c) The Author(s) 2019. Published by ECS. This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium, provided the original work is properly cited.
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收藏
页码:B3131 / B3135
页数:5
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