Proton conductivity of calix[n]arene-para-sulfonic acids (n=4, 8)

被引：18

作者：

Pisareva, A. V. ^{[1
]}

Pisarev, R. V. ^{[1
]}

Karelin, A. I. ^{[1
]}

Shmygleva, L. V. ^{[1
]}

Antipin, I. S. ^{[2
]}

Konovalov, A. I. ^{[2
]}

Solovieva, S. E. ^{[2
]}

Dobrovolsky, Yu. A. ^{[1
]}

Aldoshin, S. M. ^{[1
]}

机构：

[1] Russian Acad Sci, Inst Problems Chem Phys, Chernogolovka 142432, Moscow Region, Russia

[2] Russian Acad Sci, Kazan Sci Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2012年 / 61卷 / 10期

关键词：

proton conductivity; activation energy; IR spectroscopy; water sorption; hydrate; calix[4]arene-p-sulfonic acid; calix[8]arene-para-sulfonic acid; EXCHANGE MEMBRANES; DIHYDRATE; WATER; CALIX<6>ARENE; COMPLEX; SYSTEMS; NMR;

D O I：

10.1007/s11172-012-0263-7

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

High proton conductivity in calix[n]arene-para-sulfonic acid hydrates (n = 4, 8) reaching a value of 10(-1) Ohm(-1) cm(-1) at a relative humidity of 80% was revealed for the first time. This value is close to the record conductivity of solid proton conductors and acid water solutions. The dependence of proton transfer parameters and water quantity in the title compounds dependent on the relative humidity of air was investigated.

引用

页码：1892 / 1899

页数：8

共 50 条

[1] Proton conductivity of calix[n]arene-para-sulfonic acids (n = 4, 8)
A. V. Pisareva
R. V. Pisarev
A. I. Karelin
L. V. Shmygleva
I. S. Antipin
A. I. Konovalov
S. E. Solovieva
Yu. A. Dobrovolsky
S. M. Aldoshin
Russian Chemical Bulletin, 2012, 61 : 1892 - 1899
[2] Proton conductivity of calix[4]arene-para-sulfonic acids
Shmygleva, L. V.
Pisareva, A. V.
Pisarev, R. V.
Ukshe, A. E.
Dobrovol'skii, Yu A.
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2013, 49 (08) : 801 - 806
[3] Proton conductivity of calix[4]arene-para-sulfonic acids
L. V. Shmygleva
A. V. Pisareva
R. V. Pisarev
A. E. Ukshe
Yu. A. Dobrovol’skii
Russian Journal of Electrochemistry, 2013, 49 : 801 - 806
[4] Crystalline hydrates of calix[4]arene-para-sulfonic acid with n (n = 6–16) water molecules: a structure modeling
T. S. Zyubina
L. V. Shmygleva
R. V. Pisarev
A. S. Zyubin
A. V. Pisareva
Yu. A. Dobrovolsky
V. M. Volokhov
Russian Chemical Bulletin, 2017, 66 : 62 - 69
[5] Crystalline hydrates of calix[4]arene-para-sulfonic acid with n (n=6-16) water molecules: a structure modeling
Zyubina, T. S.
Shmygleva, L. V.
Pisarev, R. V.
Zyubin, A. S.
Pisareva, A. V.
Dobrovolsky, Yu. A.
Volokhov, V. M.
RUSSIAN CHEMICAL BULLETIN, 2017, 66 (01) : 62 - 69
[6] Effect of the structure of calix[4]arene-para-sulfonic acid on its transport properties
Shmygleva, L. V.
Sanginov, E. A.
Kayumov, R. R.
Ukshe, A. E.
Dobrovol'skii, Yu. A.
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2015, 51 (05) : 468 - 472
[7] Effect of the structure of calix[4]arene-para-sulfonic acid on its transport properties
L. V. Shmygleva
E. A. Sanginov
R. R. Kayumov
A. E. Ukshe
Yu. A. Dobrovol’skii
Russian Journal of Electrochemistry, 2015, 51 : 468 - 472
[8] Percolation model of conductivity of calix[n]arene-p-sulfonic acids
Ukshe, A. E.
Shmygleva, L. V.
Pisareva, A. V.
Bukun, N. G.
Dobrovol'skii, Yu. A.
RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2013, 49 (08) : 807 - 812
[9] Percolation model of conductivity of calix[n]arene-p-sulfonic acids
A. E. Ukshe
L. V. Shmygleva
A. V. Pisareva
N. G. Bukun
Yu. A. Dobrovol’skii
Russian Journal of Electrochemistry, 2013, 49 : 807 - 812
[10] SYNTHESIS AND ACID-BASE PROPERTIES OF CALIX[4]ARENE, CALIX[6]ARENE AND CALIX[8]ARENE PARA-SULFONIC ACIDS
SCHARFF, JP
MAHJOUBI, M
PERRIN, R
NEW JOURNAL OF CHEMISTRY, 1991, 15 (12) : 883 - 887

← 1 2 3 4 5 →