Synthesis and Photophysical Properties of Conjugated and Nonconjugated Phthalocyanine-Perylenediimide Systems

被引：11
|
作者：
Follana-Berna, Jorge [1 ]
Inan, Damla [2 ]
Blas-Ferrando, Vicente M. [1 ]
Gorczak, Natalie [2 ]
Ortiz, Javier [1 ]
Manjon, Felix [1 ]
Fernandez-Lazaro, Fernando [1 ]
Grozema, Ferdinand C. [2 ]
Sastre-Santos, Angela [1 ]
机构：
[1] Univ Miguel Hernandez, Inst Bioingn, Div Quim Organ, Elche 03202, Spain
[2] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands
来源：
JOURNAL OF PHYSICAL CHEMISTRY C | 2016年 / 120卷 / 46期
基金：
欧洲研究理事会;
关键词：
ORGANIC SOLAR-CELLS; CHARGE SEPARATION; MAGNESIUM-ION; DYAD; PHOTOSYNTHESIS; COMPLEXATION; TRANSPORT; ACCEPTOR; DYES;
D O I：
10.1021/acs.jpcc.6b07160
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The synthesis and characterization of different conjugated phthalocyanine perylenemonoimidebenzimidazole [ZnPc-PBIm(OR)(4)] and nonconjugated phthalocyanine perylenediimide [ZnPc-PDI(OR)(4)] dyads are carried out. UV-vis, H-1 NMR, and electrochemistry measurements reveal the interaction between perylene and phthalocyanine moieties in the ground state in the conjugated hybrid and the lack of interaction in the nonconjugated one. Ultrafast transient absorption measurements show that a state with substantial charge-transfer character is formed in both compounds, but the rates for the formation and recombination from this state are much faster for the conjugated compound.
引用
收藏
页码：26508 / 26513
页数：6
相关论文
共 50 条
  • [1] Synthesis and photophysical properties of novel phthalocyanine-perylenediimide-phthalocyanine triad and phthalocyanine-perylenediimide dyads
    Sun, Xiaobo
    Qiu, Wenfeng
    Wei, Donghui
    Tang, Mingsheng
    Guo, Lin
    RSC ADVANCES, 2014, 4 (49): : 25616 - 25624
  • [2] Synthesis and photophysical properties of a hydrogen-bonded phthalocyanine-perylenediimide assembly
    Seitz, Wolfgang
    Jimenez, Angel J.
    Carbonell, Esther
    Grimm, Bruno
    Salome Rodriguez-Morgade, M.
    Guldi, Dirk M.
    Torres, Tomas
    CHEMICAL COMMUNICATIONS, 2010, 46 (01) : 127 - 129
  • [3] Synthesis, characterization and photophysical properties of a melamine-mediated hydrogen-bound phthalocyanine-perylenediimide assembly
    Jimenez, Angel J.
    Calderon, Rafael M. Krick
    Salome Rodriguez-Morgade, M.
    Guldi, Dirk M.
    Torres, Tomas
    CHEMICAL SCIENCE, 2013, 4 (03) : 1064 - 1074
  • [4] Phthalocyanine-Perylenediimide Cart Wheels
    Fernandez-Ariza, Javier
    Calderon, Rafael M. Krick
    Salome Rodriguez-Morgade, M.
    Guldi, Dirk M.
    Torres, Tomas
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (39) : 12963 - 12974
  • [5] Regioisomers of Perylenediimide: Synthesis, Photophysical, and Electrochemical Properties
    Keerthi, Ashok
    Valiyaveettil, Suresh
    JOURNAL OF PHYSICAL CHEMISTRY B, 2012, 116 (15): : 4603 - 4614
  • [6] Directly Linked Zinc Phthalocyanine-Perylenediimide Dyads and a Triad for Ultrafast Charge Separation
    Zink-Lorre, Nathalie
    Font-Sanchis, Enrique
    Seetharaman, Sairaman
    Karr, Paul A.
    Sastre-Santos, Angela
    D'Souza, Francis
    Fernandez-Lazaro, Fernando
    CHEMISTRY-A EUROPEAN JOURNAL, 2019, 25 (43) : 10123 - 10132
  • [7] Control of Photoinduced Electron Transfer in Zinc Phthalocyanine-Perylenediimide Dyad and Triad by the Magnesium Ion
    Fukuzumi, Shunichi
    Ohkubo, Kei
    Ortiz, Javier
    Gutierrez, Ana M.
    Fernandez-Lazaro, Fernando
    Sastre-Santos, Angela
    JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 112 (43): : 10744 - 10752
  • [8] Synthesis, photophysical and electrochemical properties of perfluoroisopropyl substituted binuclear phthalocyanine conjugated with a butadiyne linker
    Shibata, Norio
    Das, Banibrata
    Hayashi, Masamichi
    Nakamura, Shuichi
    Toru, Takeshi
    JOURNAL OF FLUORINE CHEMISTRY, 2009, 130 (12) : 1164 - 1170
  • [9] Multichromophoric Phthalocyanine-(Perylenediimide)8 Molecules: A Photophysical Study
    Albert-Seifried, Sebastian
    Finlayson, Chris E.
    Laquai, Frederic
    Friend, Richard H.
    Swager, Timothy M.
    Kouwer, Paul H. J.
    Juricek, Michal
    Kitto, Heather J.
    Valster, Sanne
    Nolte, Roeland J. M.
    Rowan, Alan E.
    CHEMISTRY-A EUROPEAN JOURNAL, 2010, 16 (33) : 10021 - 10029
  • [10] Rational design of a phthalocyanine-perylenediimide dyad with a long-lived charge-separated state
    Blas-Ferrando, Vicente M.
    Ortiz, Javier
    Bouissane, Latifa
    Ohkubo, Kei
    Fukuzumi, Shunichi
    Fernandez-Lazaro, Fernando
    Sastre-Santos, Angela
    CHEMICAL COMMUNICATIONS, 2012, 48 (50) : 6241 - 6243
12345