Phase behavior of epoxidized soybean oil-based ionic liquid microemulsions: Effects of ionic liquids, surfactants, and co-surfactants

Epoxidized soybean oil (ESBO)-based ionic liquid microemulsions are promising alternatives for petroleum-based lubricants. This study presents the phase behavior of these microemulsions through phase manifestation, and the areas of the single-phase domain were accordingly calculated to illustrate the phase-forming capacities of the designed microemulsions. Effects of ionic liquid anions and cations, surfactant and co-surfactant chain lengths on the phase behavior, and phase-forming capacities of ESBO-based ionic liquid microemulsions were investigated. Results showed that the phase-forming capacities of the ESBO-based ionic liquid microemulsions with different ionic liquid anions and cations showed the following sequence: Tf2N--based > PF6--based > BF4--based, OMIM+-based > HMIM+-based > BMIM+- based > EMIM+-based. Given the presence of ionic liquid-ESBO amphiphilic balance in the designed systems, the ESBO-surfactant micelles achieved maximum solubilization capacity for 1-butyl-3-methyl-imidazolium tetrafluoroborate when the surfactant had approximately eight ethoxylated groups. In addition, ESBO-based microemulsion containing n-hexanol showed a higher phase-forming capacity than that containing n-butanol, and n-octanol caused a different phase behavior for the ESBO-based microemulsion because of its oilier nature than a co-surfactant. (C) 2015 Published by Elsevier B.V.