Hydrogen peroxide detection with quartz-enhanced photoacoustic spectroscopy using a distributed-feedback quantum cascade laser

被引：44
|
作者：
Ren, Wei [1 ]
Jiang, Wenzhe [1 ]
Sanchez, Nancy P. [2 ]
Patimisco, Pietro [1 ,3 ,4 ]
Spagnolo, Vincenzo [3 ,4 ]
Zah, Chung-en [5 ]
Xie, Feng [5 ]
Hughes, Lawrence C. [5 ]
Griffin, Robert J. [2 ]
Tittel, Frank K. [1 ]
机构：
[1] Rice Univ, Dept Elect & Comp Engn, Houston, TX 77005 USA
[2] Rice Univ, Dept Civil & Environm Engn, Houston, TX 77005 USA
[3] Univ Bari, Dipartimento Interateneo Fis, I-70126 Bari, Italy
[4] Politecn Bari, I-70126 Bari, Italy
[5] Corning Inc, Corning, NY 14831 USA
来源：
APPLIED PHYSICS LETTERS | 2014年 / 104卷 / 04期
基金：
美国国家科学基金会;
关键词：
TUNABLE DIODE-LASER; ORGANIC HYDROPEROXIDE; NITRIC-OXIDE; VAPOR; FORMALDEHYDE; SENSOR; AIR;
D O I：
10.1063/1.4863955
中图分类号：
O59 [应用物理学];
学科分类号：
摘要：
A quartz-enhanced photoacoustic spectroscopy sensor system was developed for the sensitive detection of hydrogen peroxide (H2O2) using its absorption transitions in the v(6) fundamental band at similar to 7.73 mu m. The recent availability of distributed-feedback quantum cascade lasers provides convenient access to a strong H2O2 absorption line located at 1295.55 cm(-1). Sensor calibration was performed by means of a water bubbler that generated titrated average H2O2 vapor concentrations. A minimum detection limit of 12 parts per billion (ppb) corresponding to a normalized noise equivalent absorption coefficient of 4.6 x 10(-9) cm(-1)W/Hz(1/2) was achieved with an averaging time of 100 s. (C) 2014 AIP Publishing LLC.
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页数：5
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