Dimethyl Ether Carbonylation to Methyl Acetate over Nanosized Mordenites

被引：83
|
作者：
Xue, Huifu [1 ]
Huang, Xiumin [1 ]
Ditzel, Evert [2 ]
Zhan, Ensheng [1 ]
Ma, Meng [1 ]
Shen, Wenjie [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
[2] BP Chem Ltd, Hull Res & Technol Ctr, Kingston Upon Hull HU12 8DS, N Humberside, England
来源：
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2013年 / 52卷 / 33期
基金：
中国国家自然科学基金;
关键词：
ACID SITES; SELECTIVE CARBONYLATION; BRONSTED ACIDITY; MOLECULAR-SIEVE; METHANOL; ZEOLITES; PERFORMANCE; CATALYSTS; OLEFIN; SIZE;
D O I：
10.1021/ie400909u
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Nanosized mordenites were found to show significantly enhanced reaction efficiency in dimethyl ether (DME) carbonylation to methyl acetate (MA) because of a greatly facilitated diffusion process. Copper incorporation into the channels of the nanosized mordenites further promoted the reaction rate, selectivity, and stability. Moreover, upon the addition of a small amount of H-2 (5-19 vol %) to the feed gas, deactivation was suppressed during DME carbonylation, whereas the catalyst stability and rate of formation of MA increased.
引用
收藏
页码：11510 / 11515
页数：6
相关论文
共 50 条
  • [1] Carbonylation of Dimethyl Ether to Methyl Acetate over SSZ-13
    Lusardi, Marcella
    Chen, Thomas T.
    Kale, Matthew
    Kang, Jong Hun
    Neurock, Matt
    Davis, Mark E.
    ACS CATALYSIS, 2020, 10 (01): : 842 - 851
  • [2] Dimethyl Ether Carbonylation to Methyl Acetate over HZSM-35
    Junlong Liu
    Huifu Xue
    Xiumin Huang
    Yong Li
    Wenjie Shen
    Catalysis Letters, 2010, 139 : 33 - 37
  • [3] Dimethyl Ether Carbonylation to Methyl Acetate over HZSM-35
    Liu, Junlong
    Xue, Huifu
    Huang, Xiumin
    Li, Yong
    Shen, Wenjie
    CATALYSIS LETTERS, 2010, 139 (1-2) : 33 - 37
  • [4] Ketene as a Reaction Intermediate in the Carbonylation of Dimethyl Ether to Methyl Acetate over Mordenite
    Rasmussen, Dominik B.
    Christensen, Jakob M.
    Temel, Burcin
    Studt, Felix
    Moses, Poul Georg
    Rossmeisl, Jan
    Riisager, Anders
    Jensen, Anker D.
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2015, 54 (25) : 7261 - 7264
  • [5] Selective carbonylation of dimethyl ether to methyl acetate on Ferrierite
    Park, So Young
    Shin, Chae-Ho
    Bae, Jong Wook
    CATALYSIS COMMUNICATIONS, 2016, 75 : 28 - 31
  • [6] Nanosized seed-derived ferrierite zeolite for a gas-phase carbonylation of dimethyl ether to methyl acetate
    Kim, Eun Jeong
    Gao, Xinhua
    Tian, Jumei
    Bae, Jong Wook
    CATALYSIS TODAY, 2023, 411
  • [7] Methyl Acetate Synthesis from Dimethyl Ether Carbonylation over Mordenite Modified by Cation Exchange
    Wang, Shurong
    Guo, Wenwen
    Zhu, Lingjun
    Wang, Haixia
    Qiu, Kunzan
    Cen, Kefa
    JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (01): : 524 - 533
  • [8] Methyl Acetate Synthesis by Dimethyl Ether Carbonylation in the Presence of Zeolites: A Review
    Kipnis, M. A.
    Volnina, E. A.
    KINETICS AND CATALYSIS, 2022, 63 (02) : 129 - 140
  • [9] Selective carbonylation of dimethyl ether to methyl acetate catalyzed by acidic zeolites
    Cheung, P
    Bhan, A
    Sunley, GJ
    Iglesia, E
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (10) : 1617 - 1620
  • [10] Isolated zinc in mordenite stabilizing carbonylation of dimethyl ether to methyl acetate
    Zhang, Zhitao
    Zhao, Na
    Ma, Kui
    Cheng, Qingpeng
    Zhang, Jing
    Zheng, Lirong
    Tian, Ye
    Li, Xingang
    CHINESE CHEMICAL LETTERS, 2019, 30 (02) : 513 - 516
12345