Isobaric vapor-liquid equilibrium for systems containing sulfur compounds

被引：3
|
作者：
Guo, Benshuai [1 ,2 ]
Bai, Juan [1 ]
Li, Yonghong [1 ,3 ]
Xia, Shuqian [1 ]
Ma, Peisheng [1 ]
机构：
[1] Tianjin Univ, Key Lab Green Chem Technol, Sch Chem Engn & Technol, Tianjin 300072, Peoples R China
[2] SINOPEC RINCIG, Res Inst Nanjing Chem Ind Grp, Nanjing 210048, Peoples R China
[3] Natl Engn Res Ctr Distillat Technol, Tianjin 300072, Peoples R China
来源：
FLUID PHASE EQUILIBRIA | 2013年 / 353卷
基金：
中国国家自然科学基金;
关键词：
Vapor-liquid equilibrium; Thiophene; Dilute solution; Multi-scale; Gasoline; 4; BINARY-SYSTEMS;
D O I：
10.1016/j.fluid.2013.05.019
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Isobaric vapor-liquid equilibrium (VLE) data for the binary systems of thiophenic compounds with three hydrocarbons in gasoline (2,3-dimethyl-1-butene, 2,3-dimethyl-2-butene and n-heptane) were measured in dilute solutions at 101.33 kPa with a modified Rose-Williams still. General Coulomb meter was used to analyze the compositions of the samples from the vapor-liquid equilibrium systems. The VLE data was compared with the calculated value by the Wilson model with the interaction parameters regressed over the entire concentration range. Results found that neither the activity coefficient model nor the Henry's model could describe the VLE behavior of the trace component in the dilute solution accurately. Thus a concept of multi-scale phase equilibrium was proposed. (C) 2013 Elsevier B.V. All rights reserved.
引用
收藏
页码：87 / 92
页数：6
相关论文
共 50 条
  • [1] Isobaric vapor-liquid equilibrium for binary systems containing benzothiophene
    Sapei, Erlin
    Pokki, Juha-Pekka
    Uusi-Kyyny, Petri
    Keskinen, Kari I.
    Alopaeus, Ville
    FLUID PHASE EQUILIBRIA, 2011, 307 (02) : 180 - 184
  • [2] Isobaric vapor-liquid equilibrium of systems containing triethyl orthoformate at 101.3 kPa
    Chen, ZX
    Hu, WM
    Lu, JG
    Li, XM
    FLUID PHASE EQUILIBRIA, 1999, 154 (01) : 89 - 98
  • [3] Isobaric Vapor-Liquid Equilibrium of Toluene and Cresol Systems
    Kang, Dong-Yuk
    Jang, Hoi-Gu
    Han, Chang-Nam
    Rho, Seon-Gyun
    Cho, Dong Lyun
    Kang, Choon-Hyoung
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2009, 47 (06): : 755 - 761
  • [4] Modeling of Isobaric Vapor-Liquid Equilibrium Data for Ionic Liquid-Containing Ternary Systems
    Noumir, A.
    Saad, B.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2022, 96 (01) : 27 - 35
  • [5] Isobaric vapor-liquid equilibrium for four binary systems of thiophene
    Bai, Juan
    Guo, Benshuai
    Xia, Shuqian
    Li, Yonghong
    Ma, Peisheng
    FLUID PHASE EQUILIBRIA, 2012, 315 : 84 - 90
  • [6] Isobaric vapor-liquid equilibrium for methyldichlorosilane + methyltrichlorosilane + dimethyldichlorosilane + benzene systems
    School of Environmental Science and Engineering, Nanchang University, Nanchang 330031, China
    不详
    Gao Xiao Hua Xue Gong Cheng Xue Bao, 2006, 6 (854-859):
  • [7] Salt effects on the isobaric vapor-liquid equilibrium for four binary systems
    Gu, FY
    Hou, YJ
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2000, 45 (03): : 467 - 470
  • [8] ESTIMATION OF ISOBARIC VAPOR-LIQUID EQUILIBRIUM DATA FOR BINARY-SYSTEMS
    MUKHERJEE, A
    CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 1973, 51 (03): : 386 - 389
  • [9] PREDICTION OF VAPOR COMPOSITION IN ISOBARIC VAPOR-LIQUID SYSTEMS CONTAINING SALTS AT SATURATION
    JAQUES, D
    FURTER, WF
    ADVANCES IN CHEMISTRY SERIES, 1972, (115): : 159 - 168
  • [10] Vapor pressure and isobaric vapor-liquid equilibrium for dichloronitrobenzene isomers
    Yao, Ganbing
    Yang, Zhipeng
    Zhang, Bin
    Xu, Hui
    Zhao, Hongkun
    FLUID PHASE EQUILIBRIA, 2014, 367 : 103 - 108
12345