Bis(4,4′-bipyridinium) dodecatungstosilicate 4,4′-bipyridine hexahydrate

被引：6
|
作者：
Ma, Feng-Xia [1 ]
Zhao, Quan [1 ]
机构：
[1] Jilin Agr Sci & Technol Coll, Jilin 132101, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2008年 / 64卷
关键词：
D O I：
10.1107/S1600536808027566
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, (C10H10N2)(2)[SiW12O40]center dot C10H8N2 center dot 6H(2)O or (4,4'-bipyH(2))(2)[SiW12O40]center dot(4,4'-bipy)center dot 6H(2)O (4,4'-bipy is 4,4'-bipyridine), was prepared under hydrothermal conditions. The asymmetric unit contains a discrete Keggin-type [SiW12O40](4-) anion (located on a twofold axis), one 4,4'-bipy (located on a twofold axis), two (4,4'-bipyH(2))(2+) cations and six uncoordinated water molecules. The polyoxoanion is constructed from a central SiO4 tetrahedron which shares its O atoms with four trinuclear W3O13 groups, each of which is made up of three edge-sharing WO6 octahedra. The water molecules and [SiW12O40](4-) anions are linked through hydrogen bonds.
引用
收藏
页码：M1224 / U96
页数：12
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