Addition of N-Acyliminium Ion Pools to Alkenes Having a Nucleophilic Moiety: Integration of Intermolecular and Intramolecular Reactions

被引：10

作者：

Ashikari, Yosuke ^{[1
]}

Kiuchi, Yohei ^{[1
]}

Takeuchi, Tomoya ^{[1
]}

Ueoka, Koji ^{[1
]}

Suga, Seiji ^{[1
]}

Yoshida, Jun-ichi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2014年 / 43卷 / 02期

关键词：

PD-CATALYZED CARBOETHERIFICATION; ASYMMETRIC-SYNTHESIS; CHEMICAL OXIDATION; COUPLING REACTIONS; ANODIC-OXIDATION; IN-SITU; CYCLOADDITION; GENERATION; HETEROCYCLES; CYCLIZATIONS;

D O I：

10.1246/cl.130947

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of electrochemically generated N-acyliminium ion pools with alkenes bearing a heteroatom nucleophilic functionality such as a hydroxy group, a carboxy group, and an oxime moiety led to intermolecular carbon carbon bond formation followed by intramolecular carbon heteroatom bond formation to give the corresponding heterocyclic compounds such as cyclic ethers, lactones, and 2-isoxazolines, respectively.

引用

页码：210 / 212

页数：3

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