Performance of Carbon Supported Fe-tetraphenylporphrin-Au as Cathodic Catalyst in Direct Formic Acid Fuel Cell

被引:0
|
作者
Ma De-Na [1 ]
Chen Wei [1 ]
Jiao Lian-Sheng [2 ]
Tang Ya-Wen [1 ]
Liu Chang-Peng [3 ]
Xing Wei [3 ]
Lu Tian-Hong [1 ,3 ]
机构
[1] Nanjing Normal Univ, Jiangsu Key Lab Biofunct Mat, Coll Chem & Environm Sci, Nanjing 210097, Peoples R China
[2] Chengde Teachers Coll Nationalities, Dept Chem, Chengde 06700, Hebei, Peoples R China
[3] Chinese Acad Sci, Changchun Inst Appl Chem, Changchun 130022, Peoples R China
关键词
direct formic acid fuel cell; iron tetraphenylporphyrin; gold; cathodic catalyst; oxygen reduction;
D O I
暂无
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The electrocatalytic performance for the oxygen reduction and formic acid tolerance ability of the carbon supported catalyst of iron tetraphenylporphyrin (FeTPP) and Au (FeTPP-Au/C) were investigated. The results indicate that the electrocatalytic activity of the FeTPP-Au/C catalyst for the oxygen reduction is much better than that of the FeTPP/C and Au/C catalyst. In addition, the FeTPP-Au/C catalyst has no electrocatalytic activity for the oxidation of formic acid. Thus, it possesses high formic acid tolerance ability suitable to be used as the cathodic catalyst in DFAFC.
引用
收藏
页码:1803 / 1806
页数:4
相关论文
共 16 条
  • [1] Formation of carbon supported PtRu alloys: an XRD analysis
    Antolini, E
    Cardellini, F
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 315 (1-2) : 118 - 122
  • [2] Study of carbon-supported Au catalyst as the cathodic catalyst in a direct formic acid fuel cell prepared using a polyvinyl alcohol protection method
    Chen, Wei
    Tang, Yawen
    Bao, Jianchun
    Gao, Ying
    Liu, Changpeng
    Xing, Wei
    Lu, Tianhong
    [J]. JOURNAL OF POWER SOURCES, 2007, 167 (02) : 315 - 318
  • [3] Ethanol oxidation on a carbon-supported Pt75Sn25 electrocatalyst prepared by reduction with formic acid:: Effect of thermal treatment
    Colmati, Flavio
    Antolini, Ermete
    Gonzalez, Emesto R.
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 2007, 73 (1-2) : 106 - 115
  • [4] Performance characterization of Pd/C nanocatalyst for direct formic acid fuel cells
    Ha, S
    Larsen, R
    Masel, RI
    [J]. JOURNAL OF POWER SOURCES, 2005, 144 (01) : 28 - 34
  • [5] A miniature air breathing direct formic acid fuel cell
    Ha, S
    Adams, B
    Masel, RI
    [J]. JOURNAL OF POWER SOURCES, 2004, 128 (02) : 119 - 124
  • [6] COBALT PHTHALOCYANINE AS A FUEL CELL CATHODE
    JASINSKI, R
    [J]. JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1965, 112 (05) : 526 - &
  • [7] NEW FUEL CELL CATHODE CATALYST
    JASINSKI, R
    [J]. NATURE, 1964, 201 (492) : 1212 - &
  • [8] Electrocatalytic oxidation of aliphatic alcohols:: Application to the direct alcohol fuel cell (DAFC)
    Lamy, C
    Belgsir, EM
    Léger, JM
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (07) : 799 - 809
  • [9] Mao Z.Q., 2005, FUEL CELL
  • [10] New fuels as alternatives to methanol for direct oxidation fuel cells
    Peled, E
    Duvdevani, T
    Aharon, A
    Melman, A
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (04) : A38 - A41