Electron-ion recombination rate coefficient measurements in a flowing afterglow plasma

被引:62
|
作者
Gougousi, T [1 ]
Golde, MF [1 ]
Johnsen, R [1 ]
机构
[1] UNIV PITTSBURGH,DEPT CHEM,PITTSBURGH,PA 15260
基金
美国安德鲁·梅隆基金会; 美国国家航空航天局;
关键词
D O I
10.1016/S0009-2614(96)01488-1
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The flowing-afterglow technique in conjunction with computer modeling of the flowing plasma has been used to determine accurate dissociative-recombination rate coefficients alpha for the ions O-2(+), HCO+, CH5+, C2H5+, H3O+, CO2+, HCO2+, HN2O+, and N2O+ at 295 K We find that the simple form of data analysis that was employed in earlier experiments was adequate and we largely confirm earlier results. In the case of HCO+ ions, published coefficients range from 1.1 x 10(-7) to 2.8 x 10(-7) cm(3)/s, while our measurements give a value of 1.9 x 10(-7) cm(3)/s.
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页码:399 / 403
页数:5
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