Rhodium-Catalyzed Oxidative Coupling of Potassium Vinyltrifluoroborate with Arenes: A Direct Access to Functionalized Styrene Derivatives

被引：1

作者：

Ma, Wenbo ^{[1
,2
,3
]}

Wang, Yang ^{[1
]}

Li, Bo ^{[1
]}

Zhou, Yunhao ^{[1
]}

Xu, Yue ^{[1
]}

Sun, Yanan ^{[4
]}

Gu, Linghui ^{[1
]}

Cheng, An ^{[5
]}

机构：

[1] Chengdu Univ, Sichuan Ind Inst Antibiot, Antibiot Res & Re Evaluat Key Lab Sichuan Prov, Chengdu 610106, Peoples R China

[2] Sichuan Univ, West China Hosp, State Key Lab Biotherapy, Chengdu 610041, Sichuan, Peoples R China

[3] Sichuan Univ, West China Hosp, Canc Ctr, Chengdu 610041, Sichuan, Peoples R China

[4] Chengdu Univ, Coll Food & Biol Engn, Chengdu 610106, Peoples R China

[5] Tohoku Univ, Grad Sch Pharmaceut Sci, Sendai, Miyagi 9808578, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2022年 / 364卷 / 22期

关键词：

C-H activation; Alkenylations; Potassium Vinyltrifluoroborate; Styrene derivatives; C-H ALKENYLATIONS; VINYL-ACETATE; PALLADIUM; SEMIHYDROGENATION; OLEFINATION; EFFICIENT; ALKENES; NANOPARTICLES; ACTIVATION; COMPLEXES;

D O I：

10.1002/adsc.202200745

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Herein, we report a Rh(III)-catalyzed direct alkenylation of arenes with readily available vinyltrifluoroborate to direct access to functionalized styrenes. This method tolerates a wide range of functional groups in 33 examples with excellent site- and regioselectivity under mild conditions. The synthetic utility was demonstrated through the further transformation of thus-obtained functionalized styrenes. Preliminary mechanistic studies indicated that the reaction probably proceeds through an Rh(III)-catalyzed C-H activation/Suzuki coupling pathway.

引用

页码：3881 / 3887

页数：7

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