(N-pyrrolidinecarbodithioato-S,S')bis(triphenylphosphine)silver(I)

被引:11
|
作者
Othman, AH [1 ]
Fun, HK [1 ]
Sivakumar, K [1 ]
机构
[1] UNIV SAINS MALAYSIA, SCH PHYS, XRAY CRYSTALLOG LAB, GEORGE TOWN 11800, MALAYSIA
关键词
D O I
10.1107/S0108270195014806
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In the title compound, [Ag(C5H8NS2)(C18H15P)(2)], the Ag atom is tetrahedrally surrounded by the two P atoms of the triphenylphosphine groups and the two S atoms of the bidentate pyrrolidinecarbodithioate ligand. The coordination polyhedron is severely distorted; the S-Ag-S angle is 68.15 (4)degrees and the remaining angles are in the range 107.23 (3)-124.43 (3)degrees. The pyrrolidine ring adopts an envelope conformation.
引用
收藏
页码:843 / 845
页数:3
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