A new mononuclear iron(III) complex containing a peroxocarbonate ligand

被引：0
|
作者：
Hashimoto, K
Nagatomo, S
Fujinami, S
Furutachi, F
Ogo, S
Suzuki, M [1 ]
Uehara, A
Maeda, Y
Watanabe, Y
Kitagawa, T
机构：
[1] Kanazawa Univ, Fac Sci, Dept Chem, Kanazawa, Ishikawa 9201192, Japan
[2] Inst Mol Sci, Okazaki, Aichi 4448585, Japan
[3] Kyushu Univ, Fac Sci, Dept Chem, Fukuoka 8120053, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 07期
关键词：
D O I：
10.1002/1521-3773(20020402)41:7<1202::AID-ANIE1202>3.0.CO;2-E
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Stabilization of a peroxocarbonate ligand by formation of a five-membered chelate ring. The mononuclear peroxocarbonate complex 1 was prepared by the reaction of a bis(μ-hydroxo)diiron(III) complex with H2O2 and CO2. Compound 1 is the first crystallographically characterized transition metal complex with a peroxocarbonate ligand. Formation of the peroxocarbonate moiety in 1 proceeds by a nucleophilic addition of a peroxide anion to CO2. Hqn = quinaldic acid.
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页码：1202 / +
页数：5
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